### 从无键共振看气相中醇的酸性顺序

1. 福州大学化学学院 福建福州 350108
• 发布日期:2015-02-25
• 通讯作者: 王文峰 E-mail:wangwf@fzu.edu.cn
• 基金资助:

福建省自然科学基金(No.2013J01361)

### The Acidity Sequence of Alcohols in Vapor Phase in Terms of No-bond Resonance

Wang Wenfeng, Yuan Yaofeng

1. College of Chemistry, Fuzhou University, Fuzhou 350108, Fujian, China
• Published:2015-02-25

Abstract:

By comparing bond energies of C—O single bond and C=O double bond, it can be predicted that the conjugate bases of alcohols are able to form C=O double bond via no-bond resonance. Since the bond energy of C—C single bond is much lower than that of the C—H single bond, methyl group is easier to stabilize alkoxide ions via no-bond resonance compared with H atom, the acidity sequence of alcohols in vapor phase is: (CH3)3COH >(CH3)2CHOH >CH3CH2OH >CH3OH. This viewpoint has been supported by the result of quantum chemistry calculation.

MSC2000:

• O611.2