大学化学 >> 2016, Vol. 31 >> Issue (5): 1-7.doi: 10.3866/PKU.DXHX201507016

今日化学 上一篇    下一篇

一步法绿色氧化环己烷制备己二酸的研究进展

李晓洁,李厚金*(),赖瑢,朱可佳,李莲云   

  • 发布日期:2016-05-23
  • 通讯作者: 李厚金 E-mail:ceslhj@mail.sysu.edu.cn
  • 基金资助:
    广东省高等教育教学改革项目;中山大学本科教学改革研究项目

Research Advances in the Green Synthesis of Adipic Acid from Cyclohexane through One-Pot Method

Xiao-Jie LI,Hou-Jin LI*(),Rong LAI,Ke-Jia ZHU,Lian-Yun LI   

  • Published:2016-05-23
  • Contact: Hou-Jin LI E-mail:ceslhj@mail.sysu.edu.cn
  • Supported by:
    广东省高等教育教学改革项目;中山大学本科教学改革研究项目

摘要:

己二酸具有巨大的工业用途及需求,然而传统的制备方法存在着高能耗、高污染等缺点,开发更加清洁绿色的制备方法是大势所趋。本文主要介绍了国内外以绿色清洁氧化剂如O2(空气)、H2O2、O3氧化环己烷一步制备己二酸的研究进展。

关键词: 环己烷, 己二酸, 一步制备, 绿色氧化

Abstract:

Adipic acid(AA) has a wide range of industrial applications and is enormously demanded. However, there are many disadvantages such as high energy consumption, environmental pollution in the current industrial process. Development of environment-friendly and effective synthetic methods is in urgent need. This review mainly introduces the latest research progresses of green synthetic methods of adipic acid by direct oxidation of cyclohexane using clean oxidants such as O2 (air), H2O2 and O3.

Key words: Cyclohexane, Adipic acid, One-pot synthesis, Green oxidation

MSC2000: 

  • O62