大学化学 >> 2017, Vol. 32 >> Issue (2): 79-88.doi: 10.3866/PKU.DXHX201603011

未来化学家 上一篇    下一篇

金(Ⅰ)化合物中的亲金相互作用

欧阳一夫,刘畅*(),于航,于乐飞   

  • 发布日期:2017-02-11
  • 通讯作者: 刘畅 E-mail:ouyangyifu@pku.edu.cn

Aurophilicity in Gold (Ⅰ) Species

Yi-Fu OUYANG,Chang LIU*(),Hang YU,Le-Fei YU   

  • Published:2017-02-11
  • Contact: Chang LIU E-mail:ouyangyifu@pku.edu.cn

摘要:

20世纪80年代,人们发现在金(Ⅰ)化合物的金原子之间存在某种相互作用,并称之为亲金相互作用。通过对这类化合物的深入研究,目前人们已经可以解释它们的形成原因、作用机理,以及理论依据。本文综述了亲金相互作用的发现、历史进展、典型实例,介绍了它们在物理、化学领域中的最新进展和应用。

关键词: 亲金相互作用, 电子相关, 磷光, 非线性光学

Abstract:

In the 1980s, interaction between gold atoms in gold (Ⅰ) species was discovered, which is afterwards named "aurophilicity". Based on in-depth researches conducted on these compounds, chemists are able to explain the reason for formation, the interacting mechanism and the theoretical foundation of them. This article reviews on the discovery of "aurophilicity", its historical development with typical examples, and its fresh applications in branches of physics and chemistry.

Key words: Aurophilicity, Electron correlation, Phosphorescence, Nonlinear optics

MSC2000: 

  • G64