大学化学 >> 2016, Vol. 31 >> Issue (10): 1-9.doi: 10.3866/PKU.DXHX201606001

今日化学 上一篇    下一篇

均相催化的醇和胺借氢反应

王超*()   

  • 发布日期:2016-11-02
  • 通讯作者: 王超 E-mail:c.wang@snnu.edu.cn
  • 基金资助:
    国家自然科学基金面上项目(21473109)

Borrowing Hydrogen Reaction with Alcohols and Amines by Homogeneous Catalysis

Chao WANG*()   

  • Published:2016-11-02
  • Contact: Chao WANG E-mail:c.wang@snnu.edu.cn
  • Supported by:
    国家自然科学基金面上项目(21473109)

摘要:

醇和胺的借氢反应是一种制备胺类化合物的绿色途径。本文介绍了借氢反应的概念,并重点介绍了均相催化的醇和胺之间借氢反应的起源、重要进展以及未来的发展趋势。

关键词: 醇, 胺, 脱氢, 金属有机, 不对称催化

Abstract:

The "Borrowing Hydrogen" reaction between alcohols and amines is a green route for accessing new amines.The concept of" Borrowing Hydrogen "reaction,the origin,and important developments,as well as future directions for "Borrowing Hydrogen" reaction of alcohols and amines by homogeneous catalysis are described in the paper.

Key words: Alcohol, Amine, Dehydrogenation, Organometallics, Asymmetric catalysis

MSC2000: 

  • G64