大学化学 >> 2017, Vol. 32 >> Issue (11): 32-44.doi: 10.3866/PKU.DXHX201707007

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TEMPO及其衍生物在有机液流电池体系中的应用

刘静嘉,张宇婷,蔡辉宇,杨娟*()   

  • 发布日期:2017-11-17
  • 通讯作者: 杨娟 E-mail:yang_juan@pku.edu.cn

TEMPO and Its Derivatives in Organic Redox-Flow Batteries

Jing-Jia LIU,Yu-Ting ZHANG,Hui-Yu CAI,Juan YANG*()   

  • Published:2017-11-17
  • Contact: Juan YANG E-mail:yang_juan@pku.edu.cn

摘要:

氧化还原液流电池是一类循环效率高、性质可调控的拥有广阔前景的储能体系。相比无机液流电池体系,以TEMPO及其衍生物作为氧化还原活性材料的有机液流电池,具有成本较低、电压较高、可逆性好、结构可调等优势。本文综述了以TEMPO及其衍生物作为氧化还原活性材料的有机液流电池的研究进展,介绍了相关的实验方法、提出了未来的研究方向。

关键词: TEMPO, 有机液流电池, 电化学, 储能体系, 有机氧化还原活性物质

Abstract:

Redox-flow batteries (RFBs) are promising candidates for sustainable energy storage systems. Compared to traditional inorganic RFBs, TEMPO-based RFBs is more advantageous in low cost, high voltage, excellent reversibility and tunable redox-active material structure. In this article, we review the research progress of RFBs using TEMPO and its derivatives as redox-active materials, introduce the related experimental methods and propose the plausible directions for future research.

Key words: TEMPO, Organic redox-flow battery, Electrochemistry, Energy-storage system, Organic redox-active material

MSC2000: 

  • G64