大学化学 >> 2018, Vol. 33 >> Issue (9): 105-110.doi: 10.3866/PKU.DXHX201801029

未来化学家 上一篇    

箭推法在高价金属(Cr, Mn, Fe)含氧酸盐氧化还原反应机理中的应用

江意达*(),蒋志威,戚博闻,钟秉辰,卞江   

  • 收稿日期:2018-01-17 发布日期:2018-09-28
  • 通讯作者: 江意达 E-mail:1700011739@pku.edu.cn

Application of Arrow-Pushing Method in the Redox Mechanism of High-Valence Metallic (Cr, Mn, Fe) Oxysalts

Yida JIANG*(),Zhiwei JIANG,Bowen QI,Bingchen ZHONG,Jiang BIAN   

  • Received:2018-01-17 Published:2018-09-28
  • Contact: Yida JIANG E-mail:1700011739@pku.edu.cn

摘要:

讨论了箭推法在解释无机高价过渡金属(Cr、Mn和Fe)化合物有关反应机理中的应用。文中引入了若干反应实例,探讨了箭推法的应用。

关键词: 反应机理, 电子转移, 箭推法, 高价金属含氧酸盐

Abstract:

In this paper, we try to use the arrow-pushing method to explain the reaction mechanisms of some high-valence transition-metallic oxysalts. Some typical examples are introduced to demonstrate the method.

Key words: Reaction mechanism, Electron transfer, Arrow-pushing method, High-valence metallic oxysalt

MSC2000: 

  • G64