大学化学 >> 2019, Vol. 34 >> Issue (7): 117-124.doi: 10.3866/PKU.DXHX201901031

未来化学家 上一篇    

硼烯化合物的合成及应用

李珺浩1,孙昉1,杜泓霖2,洪辉龙1,王琨皓1,卞江1,*()   

  1. 1 北京大学化学与分子工程学院, 北京 100871
    2 北京大学地球与空间科学学院, 北京 100871
  • 收稿日期:2019-01-24 发布日期:2019-04-09
  • 通讯作者: 卞江 E-mail:bj@pku.edu.cn

Synthesis and Applications of Borylenes

Junhao LI1,Fang SUN1,Honglin DU2,Huilong HONG1,Kunhao WANG1,Jiang BIAN1,*()   

  1. 1 College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, P. R. China
    2 School of Earth and Space Science, Peking University, Beijing 100871, P. R. China
  • Received:2019-01-24 Published:2019-04-09
  • Contact: Jiang BIAN E-mail:bj@pku.edu.cn

摘要:

含一价硼的硼烯化合物在大多数情况下是不稳定的,本文从硼烯的电子结构着手,通过前人合成的一系列硼烯化合物,综述了稳定此类化合物的通用方法。同时本文简要介绍了金属和无金属硼烯配合物及其性质,其中的一些性质已经在固氮领域得到应用。

关键词: 硼烯化合物, 主族配合物, 固氮

Abstract:

In most cases, borylenes containing boron (I) are unstable. In this article, we proceed from the electron configuration of borylene and review the common methods of stabilizing this category of compounds through a series of borylenes in literature. In addition, the article briefly introduces the metallic borylenes and non-metallic borylenes and their properties. Some of these properties have been applied in nitrogen fixation.

Key words: Borylene compound, Main group element coordination, Nitrogen fixation

MSC2000: 

  • G64