大学化学 >> 2020, Vol. 35 >> Issue (1): 92-97.doi: 10.3866/PKU.DXHX201903029

化学实验 上一篇    下一篇

多酸配位聚合物的制备与表征——推荐一个综合化学实验

辜敏*(),岳斌   

  • 收稿日期:2019-03-25 录用日期:2019-08-15 发布日期:2019-08-29
  • 通讯作者: 辜敏 E-mail:mingu@fudan.edu.cn
  • 基金资助:
    国家自然科学基金(21371035)

Synthesis and Characterization of POMs-Based Coordination Polymer: A Comprehensive Chemical Experiment

Min Gu*(),Bin Yue   

  • Received:2019-03-25 Accepted:2019-08-15 Published:2019-08-29
  • Contact: Min Gu E-mail:mingu@fudan.edu.cn
  • Supported by:
    国家自然科学基金(21371035)

摘要:

介绍了一个综合化学新实验——多酸配位聚合物的制备与表征。通过杂多酸和有机配体的合成、多酸配位聚合物的制备和性能表征,使学生了解多酸配位聚合物这一无机合成化学前沿领域,在引导学生进行材料合成及性质表征的过程中,提高学生对已学知识融会贯通的能力,提升学生学习化学的兴趣。本实验综合了无机、有机化学知识点以及实验、仪器操作和数据分析能力的培养,可纳入高年级综合化学实验。

关键词: 多酸配位聚合物, 综合化学实验, 制备与表征

Abstract:

Herein, we introduce a novel comprehensive chemical experiment called the synthesis and characterization of polyoxometalates (POMs)-based coordination polymer. Through the synthesis of POMs, organic ligand, POMs-based coordination polymer and corresponding characterization, the undergraduate students can learn about POMs-based coordination polymers, the frontier of inorganic synthetic chemistry. In the process of material synthesis and characterization, the ability of knowledge integration and the interest of chemistry learning have been improved. This experiment combines the knowledge of inorganic and organic chemistry as well as the training of experiments, instruments and data analysis capabilities, which can be used as a comprehensive chemical experiment for senior students.

Key words: POMs-based coordination polymer, Comprehensive chemical experiment, Synthesis and characterization

MSC2000: 

  • G64