大学化学 >> 2020, Vol. 35 >> Issue (7): 187-189.doi: 10.3866/PKU.DXHX201912070

所属专题： 有机化学课程与实验教学

自学之友 上一篇    下一篇

基于“结构决定性质”原则的亲核性与碱性关系新解

陈星钰1, 李欣宇1, 王智谦1,2,*()   

  1. 1 北京化工大学化学学院, 北京 100029
    2 北京化工大学教务处, 北京 100029
  • 收稿日期:2019-12-25 录用日期:2020-03-19 发布日期:2020-03-30
  • 通讯作者: 王智谦 E-mail:wangzhq@mail.buct.edu.cn

Comparison between Nucleophilicity and Basicity Using the Principle of "Structure Determines Properties"

Xingyu Chen1, Xinyu Li1, Zhiqian Wang1,2,*()   

  1. 1 College of Chemistry, Beijing University of Chemical Technology, Beijing 100029, P. R. China
    2 Office of Academic Affairs, Beijing University of Chemical Technology, Beijing 100029, P. R. China
  • Received:2019-12-25 Accepted:2020-03-19 Published:2020-03-30
  • Contact: Zhiqian Wang E-mail:wangzhq@mail.buct.edu.cn

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摘要：

针对亲核试剂亲核性和碱性的关系，从“结构决定性质”的原则出发解释了二者的一致性，结合软硬酸碱理论和空间因素解释了二者的不一致性。

关键词: 亲核试剂, 亲核性, 碱性

Abstract:

This paper provides a practical explanation of the comparison between nucleophilicity and basicity of nucleophiles. The similarities are explained based on the principle of "structure determines property", and the differences are explained by combining Hard-Soft-Acid-Base theory and the steric hindrance factor.

Key words: Nucleophile, Nucleophilicity, Basicity

MSC2000: 

  • G64