大学化学 >> 2022, Vol. 37 >> Issue (7): 2111033.doi: 10.3866/PKU.DXHX202111033

化学实验 上一篇    下一篇

三维氮掺杂碳纳米球的制备及其电化学传感性能应用——推荐一个分析化学综合实验

闫晓义1,2,*(), 马强1,2, 魏士刚1,2, 张志权1, 郭玉鹏1,2   

  1. 1 吉林大学化学学院, 长春 130012
    2 吉林大学国家级化学实验教学示范中心, 长春 130012
  • 收稿日期:2021-11-10 录用日期:2021-12-13 发布日期:2022-02-10
  • 通讯作者: 闫晓义 E-mail:yxy0305@jlu.edu.cn
  • 作者简介:闫晓义, Email: yxy0305@jlu.edu.cn
  • 基金资助:
    国家自然科学基金(20974053)

Fabrication of 3D N-Doped Carbon Nanospheres and Their Application in Electrochemical Sensing: A Comprehensive Synthetic and Analytical Experiment

Xiaoyi Yan1,2,*(), Qiang Ma1,2, Shigang Wei1,2, Zhiquan Zhang1, Yupeng Guo1,2   

  1. 1 College of Chemistry, Jilin University, Changchun 130012, China
    2 National Experimental Teaching Demonstrating Center of Chemistry, Jilin University, Changchun 130012, China
  • Received:2021-11-10 Accepted:2021-12-13 Published:2022-02-10
  • Contact: Xiaoyi Yan E-mail:yxy0305@jlu.edu.cn

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摘要：

将生物电化学传感器材料引入本科实验教学中，结合前沿科研成果设计了综合探究性化学实验——三维氮掺杂碳纳米球的制备及在谷胱甘肽检测中的应用。以三聚氰胺和炭黑为原材料，通过一步高温热解法制备了三维氮掺杂碳纳米球。通过电化学技术手段研究材料的生物传感性能，在最优化条件下成功实现了生物分子谷胱甘肽的分析检测。该实验设计充分体现了“制备合成–结构表征–分析应用”的科研逻辑思维模式，培养本科生科研自主创新能力，进而从整体上提升本科生的基本实验技能和综合应用能力。

关键词: 生物电化学传感器, 综合设计实验, 氮掺杂碳纳米球, 谷胱甘肽

Abstract:

A comprehensive exploratory chemical experiment is designed to introduce carbon-based bioelectrochemical materials into undergraduate experimental teaching. This experiment consists of preparing three-dimensional N-doped carbon nanospheres (3D-N-CB) and applying them in the electrochemical detection of glutathione. First, 3D-N-CB was synthesized via one-pot pyrolysis using melamine and carbon black as the raw materials. Subsequently, the bioelectrochemical sensing performance of 3D-N-CB was studied using various electrochemical techniques, and glutathione detection was successfully achieved under optimal conditions. This experiment can fully embody the scientific research thinking mode of synthesis-characterization-application. And it can cultivate the ability of undergraduate students to innovate independently in scientific research. Therefore, the experiment can effectively improve the basic experimental skills and comprehensive application ability of undergraduates.

Key words: Bioelectrochemical sensor, Comprehensive exploratory experiment, N-doped carbon nanospheres, Glutathione

MSC2000: 

  • G64