大学化学 >> 2016, Vol. 31 >> Issue (9): 103-107.doi: 10.3866/PKU.DXHX201601019

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Fe(PDP)催化的C―H键活化

周小洲*()   

  • 发布日期:2016-09-30
  • 通讯作者: 周小洲 E-mail:annezhou@pku.edu.cn

Activation of C―H Bonds Catalyzed by Fe(PDP) Catalytic System

Xiao-Zhou ZHOU*()   

  • Published:2016-09-30
  • Contact: Xiao-Zhou ZHOU E-mail:annezhou@pku.edu.cn

摘要:

介绍高效、高选择性的Fe(PDP)催化体系的功能,并总结其选择性规律。将此规律应用在复杂分子体系中依然可行。根据反应的选择性特点和金属催化活化碳氢键的研究结果,提出了一种机理假设。最后,讨论了Fe(PDP)体系今后的可能发展方向。

关键词: 碳氢键活化, Fe(PDP), 金属催化剂, 机理

Abstract:

The Fe(PDP) catalytic system which processes high efficiency and selectivity is introduced in this paper. Its selectivity rules have been clarified and applied to complicated organic molecule system. Based on the selectivity features of Fe(PDP) and current research advances on activation of C―H bonds by metal catalysis, a hypothetical mechanism is proposed.

Key words: C―H Activation, Fe(PDP), Metal catalyst, Mechanism

MSC2000: 

  • O6