大学化学 >> 2022, Vol. 37 >> Issue (1): 2105009.doi: 10.3866/PKU.DXHX202105009

化学史 上一篇    下一篇

光学活性和手性光谱的溯源和发展

章慧1,*(), 齐爱华2, 李丹1, 李荣兴2   

  1. 1 厦门大学化学化工学院, 福建 厦门 361005
    2 大连华洋分析仪器有限公司, 辽宁 大连 116001
  • 收稿日期:2021-05-06 录用日期:2021-06-08 发布日期:2021-07-02
  • 通讯作者: 章慧 E-mail:huizhang@xmu.edu.cn
  • 作者简介:章慧,Email: huizhang@xmu.edu.cn

Traceability and Development of Optical Activity and Chiroptical Spectroscopy

Hui Zhang1,*(), Aihua Qi2, Dan Li1, Rongxing Li2   

  1. 1 College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, Fujian Province, China
    2 Dalian Huayang Analytical Instruments Co., Ltd., Dalian 116001, Liaoning Province, China
  • Received:2021-05-06 Accepted:2021-06-08 Published:2021-07-02
  • Contact: Hui Zhang E-mail:huizhang@xmu.edu.cn

摘要:

概述了19世纪以来光学活性和手性光谱的发现和发展,着重对旋光色散(ORD)、电子圆二色(ECD)和振动圆二色(VCD)光谱的发展背景和基本原理作出介绍。其中特别提及华人科学家徐光宪和徐云洁在手性光谱发展历程中的杰出贡献。

关键词: 光学活性和手性光谱史, 旋光色散(ORD), 电子圆二色(ECD), 振动圆二色(VCD)

Abstract:

This paper presents a comprehensive overview on the discovery and development of optical activity and chiroptical spectroscopy since the nineteenth century, with emphasis on the background and basic principles of the development of optical rotatory dispersion (ORD), electron circular dichroism (ECD) and vibrational circular dichroism (VCD) spectroscopy. Therein, the outstanding contributions of Chinese scientists Guangxian Xu and Yunjie Xu in the development of chiroptical spectroscopy are specifically mentioned.

Key words: History of optical activity and chiroptical spectroscopy, Optical rotatory dispersion (ORD), Electron circular dichroism (ECD), Vibrational circular dichroism (VCD)

MSC2000: 

  • G64