大学化学 >> 2015, Vol. 30 >> Issue (4): 54-57.doi: 10.3866/pku.DXHX20150454

师生笔谈 上一篇    下一篇

高教版《基础有机化学》中两个还原反应机理的修正与补充

柏铭, 孟凡君, 赖鹏翔   

  1. 山东大学(威海)海洋学院 山东威海 264209
  • 发布日期:2015-08-14
  • 通讯作者: 柏铭 E-mail:ming_bai@sdu.edu.cn
  • 基金资助:

    山东大学(威海)教学研究与教学改革立项项目(B201309)

The Amendment of Two Mechanisms of Reduction Reactions in Fundamental Organic Chemistry (Higher Education Press)

Bai Ming, Meng Fanjun, Lai Pengxiang   

  1. Marine College, Shandong University(Weihai), Weihai 264209, Shandong, China
  • Published:2015-08-14

摘要:

在教学过程中发现高等教育出版社出版的《基础有机化学》一书中有两个经自由基负离子的还原反应(即炔烃用碱金属和液氨还原反应和Birch(伯奇)还原反应)机理有不妥和需要完善之处,对此进行了修正与补充。

关键词: 有机化学, 自由基负离子, 反应机理, 修正

Abstract:

Organic chemistry is the core course of chemistry, biology and medicine, and other disciplines. The textbook Fundamental Organic Chemistry (Higher Education Press) is adopted by many universities. We proposed amendment for two mechanisms in this book involving the radical anion intermediate, the alkynes reduction with alkali metal in liquid ammonia and the Birch reduction.

Key words: Organic chemistry, Radical anion, Mechanism, Amendment

MSC2000: 

  • O6