University Chemistry ›› 2017, Vol. 32 ›› Issue (1): 84-105.doi: 10.3866/PKU.DXHX201603010

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Hyperconjugative and Stereoelectronic Effect

Hu HONG*(),Zhao-He HUANG,Zheng-Qi CHAI,Yuan-Jin ZHANG   

  • Published:2017-01-13
  • Contact: Hu HONG E-mail:eeeqxxtg@pku.edu.cn

Abstract:

In recent years, hyperconjugation is considered as the main reason why ethane prefers cross conformation. In this article, we review the history of hyperconjugation theory, a significant part of stereoelectronic effect. Furthermore, we explore the relationship between conformation analysis, reactivity and hyperconjugation, demonstrate the significance in probing molecular structure, and also make a discussion about the hyperconjugation explanation for the preference of ethanein cross conformation.

Key words: Hyperconjugation, Ethane conformation

MSC2000: 

  • G64