University Chemistry ›› 2016, Vol. 31 ›› Issue (12): 79-82.doi: 10.3866/PKU.DXHX201604034

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Discussion about Lewis Acidity of Boron Halides

Fang WANG*(),Ren-Qing LÜ,Jian-Feng YU,Zhi-Qing ZHANG   

  • Published:2016-12-20
  • Contact: Fang WANG E-mail:wangfang@upc.edu.cn
  • Supported by:
    国家自然科学基金(51103179);中央高校基本科研业务费专项资金(16CX05013A);中国石油大学(华东)考试改革立项项目(KS-B201413)

Abstract:

It is well known that the acidity of boron halides increases in the order of BF3 < BCl3 < BBr3 when interacting with strong Lewis bases. This is contradictory to what is expected from electronegativity, which suggests that boron trifluoride (BF3) should be the strongest Lewis acid in the series. It is usually argued that the charge donation from fluorine 2p lone pairs into the empty boron 2p atomic orbital is more efficient and leads to the strongest π46 bond. But some theoretical results have shown that the overlap between the boron 2p orbital and the chlorine 3p orbital is larger than that between the boron 2p orbital and the fluorine 2p orbital. So many concepts, such as charge capacity, valence deficiency, frontier orbital theory, pyramidalization energy, maximum hardness principle, minimum electrophilicity principle etc., have been put forward to explain the acidity of boron halides. This article reviews these explanations.

Key words: Boron halides, Lewis acidity, Principle of hard and soft acids and bases

MSC2000: 

  • G64