8-羟基喹啉及其铝配合物的合成、表征及发光性能——推荐一个综合化学实验

doi:10.3866/PKU.DXHX201704010

Abstract

Abstract:

First, 8-hydroxyquinoline(HQ) was synthesized by the Skraup method, which involves basic skills of organic chemistry experiment such as reflux heating, steam distillation, crystallization and recrystallization. Secondly, the synthesized 8-hydroxyquinoline was used to prepare AlQ₃ in which Al content was measured by back titration. Finally, infrared spectra, hydrogen nuclear magnetic resonance spectra, UV-Vis absorption spectra and fluorescence emission spectra of 8-hydroxyquinoline as well as AlQ₃ were measured. This experiment covers synthesis, characterization and performance testing, facilitating students to understand and complete a basic research process.

Key words: Tris(8-hydroxyquinolinato) aluminum, Luminescence, Comprehensive chemistry experiment

MSC2000:

Zhou WANG,Jian-Xin SHI,Min PENG,Sai-Li ZHENG,Rong LAI,Lian-Yun LI,Liu-Ping CHEN. Synthesis, Characterization and Luminescence Properties of 8-Hydroxyquinoline and Tris(8-hydroxyquinolinato) Aluminum: A Comprehensive Chemistry Experiment[J].University Chemistry, 2017, 32(12): 53-59.

[1]	Quanhai Fang, Jing Yan, Shuhang Niu, Ningjing Cai, Yi Yan. A Tale of Monetary Metal [J]. University Chemistry, 2022, 37(9): 2204053-.
[2]	Xiangru Meng, Yihong Yu, Yuanfan Jiang, Yuyang Liu, Gang Li. Study on the Preparation and Proton Conductivity of a Benzotriazolyl Acetic Acid-Based HOF: Recommendation of a Green Comprehensive Chemistry Experiment [J]. University Chemistry, 2022, 37(7): 2110084-.
[3]	Sichen Ye, Qiong Chen, Qiongyou Wu, Shenghua Liu, Jun Yin, Hong Yuan. Preparation of Formaldehyde-Response Fluorescent Test Paper and the Determination of Formaldehyde: Recommending a Comprehensive Chemical Experiment [J]. University Chemistry, 2022, 37(7): 2109111-.
[4]	Zhengli Hu, Kaili Xin, Shaochuang Liu, Chengbing Zhong, Xueyuan Wu, Yi-Lun Ying, Xuanfeng Kong, Xiaodong Yu, Jianrong Zhang, Yi-Tao Long. A Comprehensive Single-molecule Experiment of Peptide Phosphorylation Detection with Biological Nanopores [J]. University Chemistry, 2022, 37(7): 2111089-.
[5]	Guangya Zhang, Jie Li, Han Zhang, Suzhi Li, Shumin Chen. Double-Color Fluorescent Fountain: Luminol Reaction Based on the Preparation of Ammonia Gas [J]. University Chemistry, 2022, 37(5): 2110011-.
[6]	Yiping Zhang, Kunyue Deng, Boxuan Zhao, Yuhao Zhang, Zhouhui Chen, Yonghong Ruan, Jinmei Zhou, Huijun Zhang, Min Lin, Shunliu Deng, Xiaoyu Cao, Yanping Ren. Synthesis of Luminol and Chemiluminescence Oscillation [J]. University Chemistry, 2022, 37(5): 2110089-.
[7]	An Li, Haoran Yu, Haoran Ma, Junpeng Zhuang. Principle and Applications of Diaryl Oxalate-Hydrogen Peroxide Chemiluminescence System [J]. University Chemistry, 2022, 37(5): 2112006-.
[8]	Wenyan Dan, Lulu Kong, Xiaogang Wang. The Phenomena of AIE and ACQ in the Photoluminescence Spectrum Experiment of Organic Molecules [J]. University Chemistry, 2022, 37(1): 2103058-.
[9]	Xueyan Wu, Yan Lü, Jixi Guo. Synthesis, Structure Characterization, and Room Temperature Phosphorescence Property of 9-(4-Bromobutyl)-9H-Carbazole Prepared by Phase Transfer Catalysis Method: Recommending a Comprehensive University Chemistry Experiment [J]. University Chemistry, 2022, 37(1): 2103055-.
[10]	Xianbo Ma, Xinhan Li, Fuqin Zhang, Minghong Chen, Yanqin Ye, Chao Huang. Preparation of Flower Soaps: A Recommendation of a Comprehensive Chemistry Experiment [J]. University Chemistry, 2021, 36(8): 2009017-.
[11]	Junxia Yu, Ruyi Zhou, Ruan Chi. A Comprehensive Chemistry Experiment on the Adsorption of Phosphate by Ferrihydrite Loaded Sugarcane Bagasse [J]. University Chemistry, 2021, 36(6): 2006044-.
[12]	Xiangru Meng, Gang Li. Synthesis of Diacetylferrocene and Analysis of Photo-ligand Exchange Reaction Product between Diacetylferrocene and 1, 10-Phenanthroline: A New and Interesting Comprehensive Chemistry Experiment [J]. University Chemistry, 2021, 36(6): 2008065-.
[13]	Lingling Wei, Huan Jiao. Study on Co-precipitation Synthesis, Structure Characterization and Photoluminescent Properties of K₂GeF₆: Mn Phosphors [J]. University Chemistry, 2020, 35(4): 112-118.
[14]	Kai Li,Huijie Lu,Yuanyuan Li,Shuangquan Zang,Benzhong Tang. A Comprehensive Experiment on Synthesis of Aggregation-Induced Emitting Salicylaldehyde Azine Using Reimer-Tiemann Reaction [J]. University Chemistry, 2020, 35(1): 53-58.
[15]	Bin Wang,Zongrui Liu,Limei Duan,Liang Xu,Suozhu Bai,Xiaohong Wang. Application of "Preparation and Luminescence Properties of Weakley-Type Rare Earth Containing Polyoxometalates" in Inorganic Chemistry Laboratory Teaching [J]. University Chemistry, 2020, 35(1): 70-75.

Synthesis, Characterization and Luminescence Properties of 8-Hydroxyquinoline and Tris(8-hydroxyquinolinato) Aluminum: A Comprehensive Chemistry Experiment

RichHTML

PDF

Like

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Metrics

Recommended 0