University Chemistry ›› 2017, Vol. 32 ›› Issue (12): 1-11.doi: 10.3866/PKU.DXHX201706036

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Application of Friedel-Crafts Alkylation Reaction in Hypercrosslinked Polymers

Wan-Kai AN*(),Lu-Lu WU,Qiu JIN,Li-Jun SHI,Zhen-Liang PAN*()   

  • Published:2017-12-19
  • Contact: Wan-Kai AN,Zhen-Liang PAN E-mail:anwk16@sina.com;panzhenliang@sina.com
  • Supported by:
    河南省高等学校重点科研项目(18A150006);国家自然科学基金(21702049)

Abstract:

Constructed mainly via Friedel-Crafts alkylation reaction, hypercrosslinked polymers (HCPs) possess significant advantages, such as easy to synthesize, porous, non-toxic, structurally stable and lightly weighted. This paper briefly describes the general reaction conditions and mechanism of the conversion. Meanwhile, the synthesis strategy of some HCP materials and their diverse applications in gas adsorption/separation, water-treatment, catalysis, and sensing etc. are also be displayed here. Additionally, we point out the further combination between Friedel-Crafts alkylation reaction and HCPs in the future.

Key words: Friedel-Crafts reaction, Hypercrosslinked polymers, Absorption, Catalysis

MSC2000: 

  • G64