立体化学教学中不对称催化科研成果的融入

doi:10.3866/PKU.DXHX201707025

Abstract

Abstract:

The concept and achievements of asymmetric catalysis can be introduced into the teaching process of organic chemistry to facilitate the teaching of stereochemistry. Via this approach, the students can better understand the asymmetric catalytic reaction and the stereochemistry. The practice of scientific presentations and research activities can not only help to consolidate the theoretical knowledge, but also allow students to develop their academic accomplishment and the ability of scientific research.

Key words: Stereochemistry, Asymmetric catalysis, Scientific research

MSC2000:

Jie YU,Hui-Hui GAO,Xiu-Li ZHANG,Ming-Jie CHU. The Integration of Scientific Achievements of Asymmetric Catalysis in the Teaching Process of Stereochemistry[J].University Chemistry, 2017, 32(12): 35-40.

References

1	Bierl B. A. ; Beroza M. ; Collier C. W. Science 1970, 170, 87.
2	Rossiter B. E. ; Katsuki T. ; Sharpless K. B. J. Am. Chem. Soc. 1981, 103, 464.
3	Blaser H. U. Adv. Synth. Catal. 2002, 344, 17.
4	邢其毅; 裴伟伟; 徐瑞秋; 裴坚. 基础有机化学, 第4版北京: 北京大学出版社, 2016.
5	林国强; 李月明; 陈耀全; 孙兴文; 陈新滋. 手性合成——不对称反应及其应用, 第5版北京: 科学出版社, 2013.
6	石枫; 屠树江; 王香善. 大学化学, 2009, 24 (5), 38.
7	蔡苹; 胡铠; 程功臻. 大学化学, 2014, 29 (3), 25.
8	石先莹. 大学化学, 2015, 30 (5), 26.
9	王剑波. 大学化学, 2000, 15 (4), 6.
10	陈庆德; 李久强. 大学化学, 2002, 17 (1), 47.
11	李楠; 刘伟军; 龚流柱. 化学进展, 2010, 22 (7), 1362.
12	Katsuki T. Synlett 2003, 3, 281.
13	谢建华; 周其林. 化学学报, 2012, 70 (13), 1427.
14	丁娅; 张灿; 华维一. 有机化学, 2003, 23 (10), 1076.
15	张俊龙; 董春娥; 韩杰; 于作龙; 张良辅. 有机化学, 2001, 21 (8), 573.
16	Parker D. Chem. Rev. 1991, 91, 1441.
17	燕远勇; 左焕培; 金子林. 分子催化, 1994, 8 (2), 151.
18	张丽; 郑土才; 牟忠岳; 潘劲松. 化工生产与技术, 2014, 21 (3), 31.
19	Trost B. M. ; Brindle C. S. Chem. Soc. Rev. 2010, 39, 1600.
20	李高伟; 王晓娟; 赵文献; 郭保国; 郑昕; 王敏灿. 有机化学, 2010, 30 (9), 1292.
21	曹映玉; 杨润升; 白冬花; 何松林; 赵妍; 杨恩翠; 郝金库. 化学试剂, 2005, 27 (2), 79.
22	傅滨; 李楠; 梁晓梅; 董燕红; 王道全. 有机化学, 2007, 27 (1), 1.
23	Hashimoto T. ; Maruoka K. Chem. Rev. 2007, 107, 5656.
24	徐利文; 夏春谷; 孙伟; 李福伟; 王红旺. 有机化学, 2003, 23 (9), 919.
25	Desimoni G. ; Faita G. ; J?rgensen K. A. Chem. Rev. 2006, 106, 3561.
26	Frohn M. ; Shi Y. A. Synthesis 2000, 14, 1979.
27	肖坤; 李欣; 沈竞康. 合成化学, 2007, 15 (1), 1.
28	Pandey G. ; Banerjee P. ; Gadre S. R. Chem. Rev. 2006, 106, 4484.
29	Davie E. A. C. ; Mennen S. M. ; Xu Y. J. ; Miller S. J. Chem. Rev. 2007, 107, 5759.
30	Yu J. ; Shi F. ; Gong L. Z. Acc. Chem. Res. 2011, 44, 1156.

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The Integration of Scientific Achievements of Asymmetric Catalysis in the Teaching Process of Stereochemistry

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