环三磷腈磺酸盐阻燃剂的合成及其在阻燃聚碳酸酯中的应用——南开大学化学学院“科研反哺教学”本科生培养创新科研实践

doi:10.3866/PKU.DXHX201912043

University Chemistry ›› 2021, Vol. 36 ›› Issue (2): 1912043.doi: 10.3866/PKU.DXHX201912043

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Synthesis of Cyclotriphosphonitrile Sulfonate Flame Retardant and Application of Flame Retardant Polycarbonate: Undergraduate "Scientific Research Feedback Teaching" Comprehensive Experiment in Nankai University

Rong Wei, Xue Wang, Shuihuan Yu, Zhekan Yao, Zhiwei Miao()

State Key Laboratory of Elemento-Organic Chemistry, College of Chemistry, Nankai University, Tianjin 300071, China

Received:2019-12-12 Accepted:2020-03-12 Published:2020-03-16
Contact: Zhiwei Miao E-mail:miaozhiwei@nankai.edu.cn

Abstract

Abstract:

In order to improve the undergraduate education quality, Nankai University has organized undergraduate innovative research activities of "One Hundred Projects". College of Chemistry combines its own feature, and promotes the combination of theoretical teaching and scientific research practice in the form of "Scientific Research Feedback Teaching". College of Chemistry gives correct guidance to students as to joining scientific research innovation training and obtains satisfactory education outcome. Here we report the synthesis of two flame retardants and their application in flame retardant polycarbonate, which is one of the "One Hundred Projects" carried out in College of Chemistry in Nankai University. In the meantime, the specific implementation process and teaching effect of the "One Hundred Projects" are introduced.

Key words: Undergraduate innovative research activity, One Hundred Projects, "Scientific Research Feedback Teaching", Cyclotriphosphonitrile sulfonate, Polycarbonate, Flame retardant

MSC2000:

Rong Wei, Xue Wang, Shuihuan Yu, Zhekan Yao, Zhiwei Miao. Synthesis of Cyclotriphosphonitrile Sulfonate Flame Retardant and Application of Flame Retardant Polycarbonate: Undergraduate "Scientific Research Feedback Teaching" Comprehensive Experiment in Nankai University[J].University Chemistry, 2021, 36(2): 1912043.

Figures/Tables 12

References 11

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样品名称	w_PC/%	w_{阻燃剂剂量(FR1)}/%	样品名称	w_PC/%	w_{阻燃剂剂量(FR2)}/%
PC/FR1-0.3	99.7	0.3	PC/FR2-0.3	99.7	0.3
PC/FR1-0.5	99.5	0.5	PC/FR2-0.5	99.5	0.5
PC/FR1-1	99	1	PC/FR2-1	99	1
PC/FR1-2	98	2	PC/FR2-2	98	2

样品名称	IDT/℃ ^a	T_5%/℃ ^b	T_10%/℃ ^c	残炭率(800 ℃)/%
FR1	70.2	86.1	101.6	33.5
FR2	126.7	261.3	497.0	51.4

样品名称	IDT/℃ ^a	T_5%/℃ ^b	T_10%/℃ ^c	残炭率(800 ℃)/%
PC	228.8	425.4	452.8	19.5
PC/FR1-0.3	450.3	487.6	500.1	24.1
PC/FR1-0.5	422.8	472.6	492.6	21.4
PC/FR1-1	450.2	462.6	470.1	19.7
PC/FR1-2	440.1	455.1	458.7	18.7
PC/FR2-0.3	448.8	482.8	487.8	19.4
PC/FR2-0.5	407.9	457.7	460.1	21.6
PC/FR2-1	408.0	465.2	471.6	19.1
PC/FR2-2	445.2	456.9	460.2	18.9

样品名称	样条厚度/mm	UL 94	样品名称	样条厚度/mm	UL 94
PC/FR1-0.3	1.0	V-2	PC/FR2-0.3	1.0	V-2
	1.5	V-2		1.5	V-2
	2.0	V-1		2.0	V-1
	3.0	V-0		3.0	V-1
PC/FR1-0.5	1.0	V-2	PC/FR2-0.5	1.0	V-2
	1.5	V-1		1.5	V-1
	2.0	V-1		2.0	V-1
	3.0	V-0		3.0	V-0
PC/FR1-1	1.0	V-2	PC/FR2-1	1.0	V-2
	1.5	V-1		1.5	V-1
	2.0	V-0		2.0	V-0
	3.0	V-0		3.0	V-0
PC/FR1-2	1.0	V-2	PC/FR2-2	1.0	V-2
	1.5	V-0		1.5	V-0
	2.0	V-0		2.0	V-0
	3.0	V-0		3.0	V-0

[1]	Ting Wang, Lei He, Jinfeng Feng, Shanyou Man, Fayang Bu, Liu Zhong, Mingjun Chen. Preparation and Flame Retardancy of Epoxy Resin as a Fire Safety Material [J]. University Chemistry, 2022, 37(5): 2111059-.
[2]	Hong-Ze GAO. The Application of Chemistry in Flame Retardancy of Fire-Protection [J]. University Chemistry, 2016, 31(1): 33-40.

Synthesis of Cyclotriphosphonitrile Sulfonate Flame Retardant and Application of Flame Retardant Polycarbonate: Undergraduate "Scientific Research Feedback Teaching" Comprehensive Experiment in Nankai University

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