生物质能源化学品乙酰丙酸酯

doi:10.3866/PKU.DXHX202004043

Abstract

Abstract:

As the emerging renewable energy, biomass energy is the fourth largest energy next to coal, oil and natural gas. Alkyl levulinates are high value-added products obtained from biomass resources, which are an important class of chemical intermediates and new energy chemicals. The application of alkyl levulinates is very broad and has potential commercial value. This article introduces the physicochemical properties and uses of levulinates, together with three synthetic methods and reaction mechanism for preparing alkyl levulinates using biomass resources as raw materials. Finally, the deficiencies of alkyl levulinates production and application is analyzed, and the development trend of the future development and utilization of alkyl levulinates is provided.

Key words: Biomass, Energy chemistry, Alkyl levulinates, Catalytic conversion

MSC2000:

Wenguang Zhao, Jie Zhu, Jingxin Shi, Xianxiang Liu. Biomass-Based Energy Chemical: Alkyl Levulinates[J].University Chemistry, 2021, 36(4): 2004043.

Figures/Tables 8

References 29

1	Gaurav N. ; Sivasankari S. ; Kiran G. S. ; Ninawe A. ; Selvin J. Sustain. Energy. Rev. 2017, 73, 205. doi: 10.1016/j.rser.2017.01.070
2	Mika L. T. ; Cséfalvay E. Á. Németh. Chem. Rev. 2018, 118, 505. doi: 10.1021/acs.chemrev.7b00395
3	Chatterjee C. ; Pong F. ; Sen A. Green Chem. 2015, 17, 40. doi: 10.1039/C4GC01062K
4	Cara P. D. ; Ciriminna R. ; Shiju N. R. ; Rothenberg G. ; Pagliaro M. ChemSusChem 2014, 7, 835. doi: 10.1002/cssc.201301027
5	Unlu D. ; Boz N. ; Ilgen O. ; Hilmioglu N. Open Chem. 2018, 16, 647. doi: 10.1515/chem-2018-0070
6	Zhou H. C. ; Song J. L. ; Fan H. L. ; Zhang B. B. ; Yang Y. Y. ; Hu J. Y. ; Zhu Q. G. ; Han B. X. Green Chem. 2014, 16, 3870. doi: 10.1039/C4GC00482E
7	Shrivastav G. ; Khan T. S. ; Agarwal M. ; Haider M. A. ACS Sustain. Chem. Eng. 2017, 5, 7118. doi: 10.1021/acssuschemeng.7b01316
8	Mukherjee A. ; Dumont M. J. ; Raghavan V. Biomass Bioenergy 2015, 72, 143. doi: 10.1016/j.biombioe.2014.11.007
9	Deemolis A. ; Essayem N. ; Rataboul F. ACS Sustain. Chem. Eng. 2014, 2, 1338. doi: 10.1021/sc500082n
10	Lomba L. ; Giner B. ; Bandres I. ; Lafuente C. ; Pino M. R. Green Chem. 2011, 13, 2062. doi: 10.1039/c0gc00853b
11	Badgujar K. C. ; Badgujar V. C. ; Bhanage B. M. Fuel Process. Technol. 2020, 197, 106213. doi: 10.1016/j.fuproc.2019.106213
12	Morawala D. H. ; Dalai A. K. ; Maheria K. C. Catal. Lett. 2019, 150, 1049.
13	Chermahini A. N. ; Nazeri M. Fuel Process. Technol. 2017, 167, 442. doi: 10.1016/j.fuproc.2017.07.034
14	Gao J. ; Kong W. ; Zhou L. ; He Y. ; Ma L. ; Wang Y. ; Yin L. Y. ; Jiang Y. J. Chem. Eng. J. 2017, 309, 70. doi: 10.1016/j.cej.2016.10.021
15	Iborra M. ; Tejero J. ; Fité C. ; Ramirez E. ; Cunill F. J. Ind. Eng. Chem. 2019, 78, 222. doi: 10.1016/j.jiec.2019.06.011
16	Tian Y. ; Zhang R. Q. ; Zhao W. G. ; Wen S. ; Xiang Y.P. ; Liu X. X. Catal. Lett. 2020, 150 doi: 10.1007/s10562-020-03253-5
17	Zhou S. L. ; Jiang D. B. ; Liu X. X. ; Chen Y. P. ; Yin D. L. RSC Adv. 2018, 8, 3657. doi: 10.1039/C7RA12994G
18	Peng L. C. ; Gao X. Y. ; Chen K. L. Fuel 2015, 160, 123. doi: 10.1016/j.fuel.2015.07.086
19	Huang Y. B. ; Yang T. ; Zhou M. C. ; Pan H. ; Fu Y. Green Chem. 2016, 18, 1516. doi: 10.1039/C5GC01581B
20	Enumula S. S. ; Koppadi K. S. ; Gurram V. R. B. ; Burri D. R. ; Kamaraju S. R. R. Sustain. Energy Fuels 2017, 1, 644. doi: 10.1039/C6SE00103C
21	Tiwari M. S. ; Gawade A. B. ; Yadav G. D. Green Chem. 2017, 19, 963. doi: 10.1039/C6GC02466A
22	Ren D. ; Fu J. ; Li L. ; Liu Y. J. ; Jin F. M. ; Huo Z. B. RSC Adv. 2016, 6, 22174. doi: 10.1039/C5RA24319J
23	Maldonado G. M. G. ; Assary R. S. ; Dumesic J. A. ; Curtiss L. A. Energy Environ. Sci. 2012, 5, 8990. doi: 10.1039/c2ee22486k
24	Zhang Z. H. ; Dong K. ; Zhao Z. B. ChemSusChem 2011, 4, 112. doi: 10.1002/cssc.201000231
25	Huang Y. B. ; Yang T. ; Lin Y. T. ; Zhu Y. Z. ; Li L. C. ; Pan H. Green Chem. 2018, 20, 1323. doi: 10.1039/C7GC02883K
26	Zhou L. P. ; Zou H. J. ; Nan J. X. ; Wu L. ; Yang X. M. ; Su Y. L. ; Lu T. L. ; Xu J. Catal. Commun. 2014, 50, 13. doi: 10.1016/j.catcom.2014.02.021
27	Chen X. L. ; Zhang X. Y. ; Hou T. ; Han L. J. ; Xiao W. H. J. Energy Chem. 2018, 27, 552. doi: 10.1016/j.jechem.2017.11.005
28	Hu X. ; Li C. Z. Green Chem. 2011, 13, 1676. doi: 10.1039/c1gc15272f
29	Ding D. Q. ; Xi J. X. ; Wang J. J. ; Liu X. H. ; Lu G. Z. ; Wang Y. Q. Green Chem. 2015, 17, 4037. doi: 10.1039/C5GC00440C

乙酰丙酸酯	分子式	分子量	密度/(g·mL^-1, at 25 ℃)	熔点/℃	沸点/℃	折光率(at 20 ℃)	闪点/℃
乙酰丙酸甲酯	C₆H₁₀O₃	130.14	1.051	-24	196	1.422	72
乙酰丙酸乙酯	C₇H₁₂O₃	144.17	1.016	-33	206	1.422	90
乙酰丙酸丙酯	C₈H₁₄O₃	158.19	0.981	N/A	218	1.421	88
乙酰丙酸异丙酯	C₈H₁₄O₃	158.19	0.984	N/A	209	1.442	N/A
乙酰丙酸正丁酯	C₉H₁₆O₃	172.22	0.974	N/A	238	1.427	197
乙酰丙酸异丁酯	C₉H₁₆O₃	172.22	0.967	N/A	228	1.425	N/A

[1]	Haibo Lei, Yanling Xu, Jian Ren, Wen Liu. Curriculum Construction of "Biomass Functional Material Comprehensive Laboratory" under the Background of New Agricultural Science [J]. University Chemistry, 2022, 37(8): 2108072-.
[2]	Teng Ma, Yaqin Wang. Revisiting Classic Cases of Original Discoveries and Inventions: Fischer-Tropsch Process in Chemistry [J]. University Chemistry, 2021, 36(6): 2102030-.
[3]	Ming Guo, Jue Wang, Man Xiong, Ronghui Wu, Xuejuan Yang, Jianzhong Zhou, Minghui Li, Jiajun Li. Development of the Virtual Simulation Experiment of Preparation of Biomass Pyrolysis Products and HPLC Detection of Its Components [J]. University Chemistry, 2020, 35(12): 237-246.
[4]	Gang Fu, Nanfeng Zheng, Bin Ren, Xin Lü, Ye Wang, Zhongqun Tian, Yaxian Zhu. Construction and Practice for Energy Chemistry Majors in Xiamen University [J]. University Chemistry, 2020, 35(10): 59-64.
[5]	Shuyong Zhang, Yaxian Zhu, Jichuan Huo, Lijuan Song, Hualong Xu, Lansun Zheng. Suggestions for "Emerging Engineering Education" Reform for Chemistry-Related Majors [J]. University Chemistry, 2020, 35(10): 6-10.
[6]	Hualong Xu, Yaxian Zhu, Shuyong Zhang, Lansun Zheng. Discussion on Emerging Engineering Education Reform of "Energy Chemistry" Based on Investigation of Some Fossil Energy Industries [J]. University Chemistry, 2020, 35(10): 28-32.
[7]	Yaxian Zhu, Hualong Xu, Shuyong Zhang, Nanfeng Zheng, Lansun Zheng. Suggestions on the Development of "Energy Chemistry" [J]. University Chemistry, 2020, 35(10): 23-27.

Biomass-Based Energy Chemical: Alkyl Levulinates

RichHTML

PDF

Like

Knowledge

Abstract

Cite this article

share this article

Figures/Tables 8

References 29

Related Articles 7

Metrics

Recommended 0