双乙酰基二茂铁的合成及其与1, 10-邻菲啰啉之间的光配体交换反应产物剖析——推荐一个新颖有趣的综合化学实验

doi:10.3866/PKU.DXHX202008065

Abstract

Abstract:

1, 1-diacetylferrocene (DAF) was synthesized through Friedel-Crafts acylation reaction by using ferrocene and acetylchloride as starting materials. This process involves basic laboratory skills, such as low temperature control, anhydrous and anoxic operation, extraction, vacuum distillation and recrystallization. The photo-ligand exchange reaction between DAF and 1, 10-phenanthroline (phen) was carried out under visible light irradiation due to the photosensitivity of DAF and the strong chelating ability of phen. Phen substituted acetyl cyclopentadiene ligand, and produced complex[Fe(phen)₃](C₅H₄COCH₃)₂·CH₃CN·2H₂O. The composition of the photoreaction product was determined by means of powder X-ray diffraction, elemental analysis, infrared spectrum and ¹H NMR spectra. This comprehensive chemistry experiment is appropriate in difficulty, and the testing methods are diversified, which enables junior or senior undergraduates to complete a basic scientific research training process independently on the basis of comprehensive laboratory (Ⅰ) and basic inorganic, analytical and organic chemistry laboratories.

Key words: 1, 1-Diacetylferrocene, 1, 10-Phenanthroline, Photo-ligand exchange reaction, Comprehensive chemistry experiment

MSC2000:

Xiangru Meng, Gang Li. Synthesis of Diacetylferrocene and Analysis of Photo-ligand Exchange Reaction Product between Diacetylferrocene and 1, 10-Phenanthroline: A New and Interesting Comprehensive Chemistry Experiment[J].University Chemistry, 2021, 36(6): 2008065.

Figures/Tables 4

References 20

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6小时	12小时	18小时
模块1	模块1+模块2	模块1+模块2+模块3
模块2 (实验室提供DAF)	模块1+模块3
模块3 (实验室提供DAF)	模块2+模块3 (实验室提供DAF)

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Synthesis of Diacetylferrocene and Analysis of Photo-ligand Exchange Reaction Product between Diacetylferrocene and 1, 10-Phenanthroline: A New and Interesting Comprehensive Chemistry Experiment

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