纳米Fe2O3和Fe3O4的制备及其催化高氯酸铵热分解性能的研究——一个仪器分析综合实验

doi:10.3866/PKU.DXHX201711002

University Chemistry ›› 2018, Vol. 33 ›› Issue (4): 51-56.doi: 10.3866/PKU.DXHX201711002

• Chemistry Laboratory • Previous Articles Next Articles

Preparation of Fe₂O₃ and Fe₃O₄ Nanoparticles and the Catalytic Performance for Thermal Decomposition of Ammonium Perchlorate

Xiaoling WANG,Chuqing GONG,Yalan ZHONG,Chi HUANG*()

National Demonstration Center for Experimental Chemistry Education(Wuhan University), College of Chemistry and Molecular Sciences, Wuhan University, Wuhan 430072, P. R. China

Received:2017-11-01 Published:2018-04-08
Contact: Chi HUANG E-mail:chihuang@whu.edu.cn
Supported by:
国家“基础学科拔尖学生培养试验计划”研究课题(20160210);湖北省高等学校教学研究项目(2014011)

Abstract

Abstract:

The Fe₃O₄ and Fe₂O₃ nanoparticles were successfully prepared by hydrothermal method. The Fe₃O₄ and Fe₂O₃ nanoparticles were characterized by X-ray powder diffraction (XRD) and the transmission electron microscopy (TEM).The obtained Fe₃O₄ and Fe₂O₃ were spheres and the diameter was about 10-20 nm. The catalysis activity of Fe₃O₄ and Fe₂O₃ on the thermal decomposition of ammonium perchlorate (AP) was appraised by thermalanalysis (TG-DSC). It was found that Fe₂O₃ and Fe₃O₄ nanoparticles had high catalysis activity on decomposition of AP. The results can be used as a comprehensive experimental course in the instrument analysis laboratroy. The students can learn the hydrothermal method and learn how to use XRD, thermal analysis and other means to characterize the compounds.

Key words: Fe₂O₃ nanoparticles, Fe₃O₄ nanoparticles, Ammonium perchlorate, Thermal analysis, Catalysis

MSC2000:

G643

Xiaoling WANG,Chuqing GONG,Yalan ZHONG,Chi HUANG. Preparation of Fe₂O₃ and Fe₃O₄ Nanoparticles and the Catalytic Performance for Thermal Decomposition of Ammonium Perchlorate[J].University Chemistry, 2018, 33(4): 51-56.

[1]	Ziqiang Deng, Hongjie Song, Rui Liu, Yi Lv. Microplastics Travel Agency [J]. University Chemistry, 2022, 37(9): 2110069-.
[2]	Quanhai Fang, Jing Yan, Shuhang Niu, Ningjing Cai, Yi Yan. A Tale of Monetary Metal [J]. University Chemistry, 2022, 37(9): 2204053-.
[3]	Yan Wang, Qitong Zhang, Bin Zhang, Yu Wang. Amazing Photocatalysis [J]. University Chemistry, 2022, 37(9): 2203098-.
[4]	Ming Zhao, Yurong Xu, Jing Lin, Hu Chen. N-Heterocyclic Carbene Catalyzed Michael Addition Reaction [J]. University Chemistry, 2022, 37(6): 2108056-.
[5]	Xiaowei Li, Lai Qin, Qixin Xing, Qing Liu, Lei Zhang. Synergistic Effect of "Science" and "Education" to Cultivate Outstanding Innovative Talents under Background of National First-Class Undergraduate Majors Construction: Taking the Photocatalytic Degradation of MO with BiOI as an Example [J]. University Chemistry, 2022, 37(6): 2107016-.
[6]	Wei Wen, Chaoxing Li, Fangxiu Ye, Jingfeng Li, Qixiang Guo. Catalytic Asymmetric Synthesis of Chiral α-Amino Ketones [J]. University Chemistry, 2022, 37(5): 2111009-.
[7]	Di Zhang, Tian Xia, Yongxiang Luo, Xi Wang. Visible-Light-Driven Biomimetic Catalytic Green Synthesis and Quantitative Analysis of Coumarin Derivatives Based on Spectrophotometry [J]. University Chemistry, 2022, 37(5): 2111090-.
[8]	Xiangqing Feng, Haifeng Du. The 2021 Nobel Prize in Chemistry: The Simpler the Better [J]. University Chemistry, 2022, 37(1): 2112014-.
[9]	Mengshi Jin, Jiabin Shen, Jun Xu, Pengfei Zhang, Wanmei Li. Green Synthesis of Anticancer Quinoxalinone JNK3 Inhibitors: A Proposed Comprehensive Chemical Experiment [J]. University Chemistry, 2022, 37(1): 2104034-.
[10]	Xueyan Wu, Yan Lü, Jixi Guo. Synthesis, Structure Characterization, and Room Temperature Phosphorescence Property of 9-(4-Bromobutyl)-9H-Carbazole Prepared by Phase Transfer Catalysis Method: Recommending a Comprehensive University Chemistry Experiment [J]. University Chemistry, 2022, 37(1): 2103055-.
[11]	Yuzi Huang, Maosheng Jiang, Yuexu Lin. Experimental Design and Teaching Effect of Maltose Syrup Preparation [J]. University Chemistry, 2021, 36(8): 2011034-.
[12]	Chuanfeng Liu, Jiacheng Liu, Peihong Gao, Junyan Liang, Yanhong Bai, Wen Zhang, Dan Xiang, Min Hu. Study on the Controlled Preparation, Analysis and Catalytic Properties of Cu₂O Crystals [J]. University Chemistry, 2021, 36(8): 2011015-.
[13]	Teng Ma, Yaqin Wang. Revisiting Classic Cases of Original Discoveries and Inventions: Fischer-Tropsch Process in Chemistry [J]. University Chemistry, 2021, 36(6): 2102030-.
[14]	Yanqin Li, Jie Zhang, Wei Wang, Jinfeng Yang, Feng Yu. Laboratory Teaching Exploration for Science and Education Integration under Background of "Double First-Class" Construction: Taking TiO₂ for Photocatalytic Degradation of Dyes as an Example [J]. University Chemistry, 2021, 36(6): 2008044-.
[15]	Yaqin Wang, Teng Ma. Revisiting Classic Cases of Original Discoveries and Inventions: Ammonia Synthesis in Chemistry [J]. University Chemistry, 2021, 36(4): 2008035-.

Preparation of Fe₂O₃ and Fe₃O₄ Nanoparticles and the Catalytic Performance for Thermal Decomposition of Ammonium Perchlorate

RichHTML

PDF

Like

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Metrics

Recommended 0

Preparation of Fe2O3 and Fe3O4 Nanoparticles and the Catalytic Performance for Thermal Decomposition of Ammonium Perchlorate

RichHTML

PDF

Like

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Metrics

Recommended 0

Preparation of Fe₂O₃ and Fe₃O₄ Nanoparticles and the Catalytic Performance for Thermal Decomposition of Ammonium Perchlorate