Fe(II)-Pd(II)异金属有机分子笼的制备及其物化性能研究——推荐一个新颖的综合化学实验

doi:10.3866/PKU.DXHX202006045

Abstract

Abstract:

A Fe(II)-Pd(II) heteronuclear metal-organic cages (MOC-42) is obtained by stepwise synthesis. The solution structure of MOC-42 is characterized by NMR, and the decomposition kinetics is studied by UV-Vis absorption spectra. This new comprehensive chemistry experiment is appropriate in difficulty, and the studying methods are various, which enables students to flexibly apply the existing basic chemical knowledge and modern instrument techniques. It is beneficial to train the ability of initiative thinking and practice competency of the students.

Key words: Metal-organic cage, Stepwise assembly, Decomposition kinetics, Physical chemistry property

MSC2000:

Mei Pan, Chaojie Li, Yajun Hou, Chengyong Su. Synthesis and Physical Chemistry Property Study of a Fe(II)-Pd(II) Heteronuclear Metal-Organic Cag: A New Comprehensive Chemistry Experiment[J].University Chemistry, 2021, 36(6): 2006045.

Figures/Tables 8

References 14

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Synthesis and Physical Chemistry Property Study of a Fe(II)-Pd(II) Heteronuclear Metal-Organic Cag: A New Comprehensive Chemistry Experiment

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