University Chemistry ›› 2015, Vol. 30 ›› Issue (1): 64-67.doi: 10.3866/PKU.DXHX20150113

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The Transition State Theory for Elementary Reaction

Liu Guojie, Hei Encheng   

  1. Department of Chemistry, East China University of Science and Technology, Shanghai 200237, China
  • Published:2015-02-25

Abstract:

Based on the view that macro elementary reaction is the transition from micro chemical reaction to macro chemical reaction, the transition state theory was interpreted by combining the features of activated complex and micro chemical reaction model, and a practical deduction was obtained.

Key words: Transition state theory, Activated complex, Decomposition frequency, Mean vibration quantum number, Modified Arrhenius equation

MSC2000: 

  • O643