University Chemistry ›› 2019, Vol. 34 ›› Issue (3): 68-76.doi: 10.3866/PKU.DXHX201807013

• Future Chemist • Previous Articles     Next Articles

Application of Arrow-Pushing in the Disproportionation of Halogen Oxoanions

Tianyi YANG1,*(),Qing ZENG2,Gan WANG2,Yidan MIAO3   

  1. 1 College of Life Sciences, Peking University, Beijing 100871, P. R. China
    2 College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, P. R. China
    3 College of Yuanpei, Peking University, Beijing 100871, P. R. China
  • Received:2018-07-05 Accepted:2018-08-31 Published:2019-03-09
  • Contact: Tianyi YANG E-mail:yty@pku.edu.cn

Abstract:

The article uses the disproportionation of chlorate and hypobromite as examples to analyze the application of arrow-pushing in the disproportionation of halogen oxoanions. Based on the experimental results, we have discussed the rationality of each possible mechanism we proposed based on electronic structure methods. All these efforts are put to demonstrate the way to introduce basic organic-style arrow-pushing into inorganic field.

Key words: Halogen oxoanion, Disproportionation, Inorganic reaction, Mechanism

MSC2000: 

  • G64