利用Reimer-Tiemann反应合成水杨醛缩肼聚集诱导发光分子的综合实验

doi:10.3866/PKU.DXHX201904010

University Chemistry ›› 2020, Vol. 35 ›› Issue (1): 53-58.doi: 10.3866/PKU.DXHX201904010

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A Comprehensive Experiment on Synthesis of Aggregation-Induced Emitting Salicylaldehyde Azine Using Reimer-Tiemann Reaction

Kai Li^1,*(),Huijie Lu¹,Yuanyuan Li²,Shuangquan Zang¹,Benzhong Tang^3,*()

¹ College of Chemistry and Molecular Engineering, Zhengzhou University, Zhengzhou 450001, P. R. China
² College of Chemistry, Chemical and Environmental Engineering, Henan University of Technology, Zhengzhou 450001, P. R. China
³ Department of Chemistry, The Hong Kong University of Science & Technology, Hong Kong, P. R. China

Received:2019-04-09 Accepted:2019-05-08 Published:2019-05-28
Contact: Kai Li,Benzhong Tang E-mail:likai@zzu.edu.cn;tangbenz@ust.hk
Supported by:
国家自然科学基金(21501150);香港创新科技署基金(ITC-CNERC14SC01);广西有色金属及特色材料加工重点实验室开放基金(2019GXYSOF12)

Abstract

Abstract:

Aggregation-induced emission (AIE) molecules exhibit intense emission in aggregated state but weak or even no fluorescence in dispersed state. The first AIE molecule was reported in 2001. Since then, various of AIE molecules were developed successively, which were widely applied in fields of photoelectric materials, fluorescence chemosensors and bioimaging, etc. Salicylaldehyde azine is a classic AIE molecule with the merits of simple synthesis and intense luminescence. In this comprehensive experiment, the precursor salicylaldehyde is first synthesized using Reimer-Tiemann reaction. Then it reacts with azine to obtain the AIE molecule of salicylaldehyde azine. Through the experiment, students will practice the synthetic method of Reimer-Tiemann reaction and grasp the origination of AIE characteristics of salicylaldehyde azine. Also, students will learn about the applications of AIE molecules through class and network learning.

Key words: Aggregation-induced emission, Reimer-Tiemann reaction, Salicylaldehyde azine, Fluorescence, Comprehensive chemistry experiment

MSC2000:

Kai Li,Huijie Lu,Yuanyuan Li,Shuangquan Zang,Benzhong Tang. A Comprehensive Experiment on Synthesis of Aggregation-Induced Emitting Salicylaldehyde Azine Using Reimer-Tiemann Reaction[J].University Chemistry, 2020, 35(1): 53-58.

Figures/Tables 6

References 17

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A Comprehensive Experiment on Synthesis of Aggregation-Induced Emitting Salicylaldehyde Azine Using Reimer-Tiemann Reaction

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