太阳能驱动Ni-N掺杂多孔碳高效电催化还原CO2为CO

doi:10.3866/PKU.DXHX201912044

Abstract

Abstract:

The electroreduction of CO₂ into value-added chemicals and fuels has garnered a broad interest by using renewable clean energy, due to both alleviating global warming and completing the carbon cycle. Herein, a high-performance Ni-N doped porous carbon catalyst was prepared through pyrolysis of hydrogen containing peptone, NiCl₂, and NaCl made by a freeze dry method. The Ni-N-doped porous carbon catalyst displayed an excellent performance of CO₂ electroreduction with a Faraday efficiency of 92.0% at -0.66 V (vs. RHE), 550 mV overpotential, and 2.5 mA·cm^-2 current density. The catalytic performances were attributed to the Ni-N active sites and porous structures. In addition, CO₂ electroreduction to CO was performed continuously by using solar energy, which may provide a valuable reference for carbon cycle in future.

Key words: Ni-N doped porous carbon, CO₂ electroreduction, Solar energy, CO product

MSC2000:

Ding Shaosong, Yue Tong, Wang Xingpu, Gao Jianan, Zhu Ying. Ni-N Doped Porous Carbon for Electrocatalytic Reduction of CO₂ into CO Driven by Solar Energy[J].University Chemistry, 2020, 35(4): 1-9.

Figures/Tables 9

References 32

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催化剂	电解液	工作电压	产物效率	参考文献
Ni-N掺杂多孔碳(本工作)	0.5 mol?L^?1 KHCO₃	?0.66 V vs. RHE	CO：92.0%
Ni SAs/N-C	0.5 mol?L^?1 KHCO₃	?1.00 V vs. RHE	CO：71.9%	Zhao et al. ^[28]
Hexagonal Zn	0.5 mol?L^?1 KHCO₃	?0.95 V vs. RHE	CO：85.4%	Won et al. ^[29]
AuNP-GNR	0.5 mol?L^?1 KHCO₃	?0.47 V vs. RHE	CO：87.0%	Rogers et al. ^[30]
COF-367-Co	0.5 mol?L^?1 KHCO₃	?0.67 V vs. RHE	CO：91.0%	Lin et al. ^[31]
Au cathode	0.5 mol?L^?1 KHCO₃	?0.68 V vs. RHE	CO：91.0%	Hori et al. ^[32]

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Ni-N Doped Porous Carbon for Electrocatalytic Reduction of CO₂ into CO Driven by Solar Energy

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Ni-N Doped Porous Carbon for Electrocatalytic Reduction of CO₂ into CO Driven by Solar Energy