氢元素教学内容的重构
李晖, 谭君蕊

Updating the Teaching Content of Hydrogen Element
Hui Li, Junrui Tan
表2 水溶液中钴超分子配合物的59Co NMR参数[15]
配合物Chemical shiftRh/nmτc × 10?11/s(e2qQ/h)’/MHzT1/ms
K3[Co(CN)6]1.2394.5
K3[Co(CN)6] (pH>11)0.000.35138
[12]*aneN4[Co(CN)6]?4.350.483.80.9768.8
[18]aneN6[Co(CN)6]?12.880.609.52.165.6
[24]aneN8[Co(CN)6]?6.540.609.51.0523.4
[16]aneN4[Co(CN)6]?1.750.483.80.72124
[24]aneN6[Co(CN)6]?12.210.556.61.7112.9
[32]aneN8[Co(CN)6]?12.580.556.61.4318.5