基础有机化学中立体电子效应

doi:10.3866/PKU.DXHX201811001

University Chemistry ›› 2018, Vol. 33 ›› Issue (12): 113-120.doi: 10.3866/PKU.DXHX201811001

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Stereoelectronic Effects in Fundamental Organic Chemistry

Ping LÜ*(),Yanguang WANG

Department of Chemistry, Zhejiang University, Hangzhou 310027, P. R. China

Received:2018-11-02 Published:2018-12-14
Contact: Ping LÜ E-mail:pinglu@zju.edu.cn

Abstract

Abstract:

This article describes the concept of stereoelectronic effects in fundamental organic chemistry and summarizes such specific phenomenon through formation of covalent bonds, resonance structures, rearrangement of carbocations, formation of enolate anions, bimolecular nucleophilic substitution of haloalkanes, elimination of halocyclohexanes, and electrophilic addition of cyclohexenes.

Key words: Stereochemistry, Stereoelectronic effect, Orbital orientation

Ping LÜ,Yanguang WANG. Stereoelectronic Effects in Fundamental Organic Chemistry[J].University Chemistry, 2018, 33(12): 113-120.

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Stereoelectronic Effects in Fundamental Organic Chemistry

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