箭推法视角下对卤素含氧酸根歧化反应的思考
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杨天怡,曾庆,王淦,苗译丹
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Application of Arrow-Pushing in the Disproportionation of Halogen Oxoanions
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Tianyi YANG,Qing ZENG,Gan WANG,Yidan MIAO
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表4 298 K、不同条件下速率方程(5)的k1值
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| pH | 介质/缓冲溶液a | 103k1/(mol−1∙L∙s−1) | 参考文献 | | 7.5 | 硼酸盐 | 2.4b | [10] | | 7.9 | 总浓度0.4 mol∙L−1的硼酸盐 | 1.3 | [11] | | 8.5 | 硼酸盐 | 1.6c | [10] | | 8.84 | 硼酸盐 | 0.83c | [9] | | 9.5 | 硼酸盐 | 1.1c | [10] | | 10.0 | 硼酸盐 | 0.025b | [10] | | 12 | NaOH | 0.00036b | [10] | | 12.8 | NaOH | 0.00026c | [12] |
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