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表2 硫酸铜中铜含量测定计算表(临近终点加入KSCN)
${c_{{\rm{CuS}}{{\rm{O}}_{\rm{4}}}}}$/(mol·L?1)次数${c_{{\rm{N}}{{\rm{a}}_{\rm{2}}}{{\rm{S}}_{\rm{2}}}{{\rm{O}}_{\rm{3}}}}}$/(mol·L?1) *${V_{{\rm{KI}}}}$/mL${V_{{\rm{N}}{{\rm{a}}_{\rm{2}}}{{\rm{S}}_{\rm{2}}}{{\rm{O}}_{\rm{3}}}}}$/mL **${V_{{\rm{KSCN}}}}$/mL${V_{{\rm{N}}{{\rm{a}}_{\rm{2}}}{{\rm{S}}_{\rm{2}}}{{\rm{O}}_{\rm{3}}}}}$/mL${\rho _{{\rm{Cu}}}}$/(g·L?1)${\rho _{{\rm{Cu}}}}$/(g·L?1) *RAD/%
0.025 1 0.02707 4 19.50 2.5 22.75 1.565 1.568 0.10
2 0.02707 4 20.00 2.5 22.80 1.569
3 0.02707 4 19.80 2.5 22.80 1.569
0.05 1 0.05276 8 22.50 5 23.88 3.203 3.200 0.06
2 0.05276 8 22.00 5 23.85 3.199
3 0.05276 8 22.60 5 23.85 3.199
0.1 1 0.1024 8 19.00 10 20.25 5.271 5.268 0.07
2 0.1024 8 19.00 10 20.25 5.271
3 0.1024 8 19.00 10 20.22 5.263