利用物理化学基本原理甄别科技文献数据计算的合理性
那立艳, 张丽影, 支德福, 张树彪
Discrimination of the Rationality of Data Calculation in Literature by Basic Principles of Physical Chemistry
Liyan Na, Liying Zhang, Defu Zhi, Shubiao Zhang
表1
MIL-101吸附BA的热力学数据
T
/K
10
?3
K
L
/(L·mg
?1
)
Δ
G
?
/(kJ·mol
?1
)
Δ
H
?
/(kJ·mol
?1
)
Δ
S
?
/(J·mol
?1
·K
?1
)
298
6.29
?4.55
?11.27
?22.65
308
5.19
?4.22
318
4.73
?4.11