诺贝尔化学奖类大学生创新实验——Suzuki偶联反应制备DPP类荧光染料

熊就凯, 赵美娟, 王亚男, 边刚, 戎瑞雪, 王克让

Innovative Experiment for Students Based on Nobel Prizes in Chemistry: Construction of Fluorescent DPP Derivative by Suzuki Reaction

Jiukai Xiong, Meijuan Zhao, Yanan Wang, Gang Bian, Ruixue Rong, Kerang Wang

图2 ABDPP的合成路线 a) 2-Methyl-2-butanol, Sodium tert-pentoxide, r.f., 3 h, 73%；b) Potassium tert-butoxide, DMF, 60 ℃, 4 h, 80%；c) K2CO3, THF, Pd(PPh3)4, 80 ℃, 3 h, 53%