取代环己酮还原立体选择性的过渡态理论解释 |
| 李佳, 胡潇, 王健春, 于凯歌, 耿诗宁, 孟祥福 |
|
Explanation of the Transition State Theory of the Stereoselectivity of the Reduction of Substituted Cyclohexanone |
| Jia Li, Xiao Hu, Jianchun Wang, Kaige Yu, Shining Geng, Xiangfu Meng |
| 图1 (a) NaBH4赤道向进攻环己酮过渡态;(b) NaBH4轴向进攻环己酮过渡态;(c) 还原剂沿轴向进攻3, 3, 5-三甲基环己酮;(d) 还原剂沿赤道向进攻3, 3, 5-三甲基环己酮 |
|