光电化学在有机合成中的应用
蔡浩然, 姚夏奕, 曹宇超, 陆泽鹏, 卞江
Applications of Photoelectrochemistry in Organic Synthesis
Haoran Cai, Xiayi Yao, Yuchao Cao, Zepeng Lu, Jiang Bian
表2
染料分子的吸收峰与氧化(还原)电位
基态
Red/Ox
[a]
I
max
[b]
/nm
E
1/2
[c]
/V
vs.
SCE
DCA
[
40
]
Red
450, 480, 510
−0.82 → −3.2
PTZ
[
40
]
Ox
514, 772
+0.70 → +2.9
TAC
+
[
25
]
Ox
450, 500, 598
+1.26 → +3.3
RFT
[
27
]
Ox
440
+1.67
Mes-Acr
+
[
41
]
Ox
359, 422
+2.06
4CzIPN
[
42
]
Ox
539
+1.43
DDQ
[
43
]
Ox
465
+3.18