几种常见脂肪醇的氢键结构探究——红外光谱测定结合量化计算的实验
刘禹, 郑纪鸣, 宗陈纳言, 吴红, 胡万群

Combining Infrared Spectroscopy Experiment with Quantum Chemical Calculations to Study Hydrogen Bond in Several Aliphatic Alcohol and CCl4 Solutions
Yu Liu, Jiming Zheng, Nayan Zongchen, Hong Wu, Wanqun Hu
表3 计算的四种脂肪醇(乙醇、正丙醇、异丙醇和正丁醇)的O―H振动频率ν (cm−1)
脂肪醇单体二聚体环状三聚体链状三聚体
νOHνBonded OHνFree OHνBonded OHνBonded OHνFree OH
乙醇3694.053483.453681.973371.023379.603689.36
3432.153427.58
3435.36
正丙醇3695.953504.853695.363373.363376.253691.71
3434.923425.34
3436.91
异丙醇3682.543487.773684.653358.663379.463678.86
3417.033424.85
3432.37
正丁醇3694.993503.323694.273374.233380.123691.13
3436.223428.25
3436.83