Cu-Zn原电池标准电动势测定实验的计算化学设计

刘宇昂, 刘晓红, 李姝, 叶世海, 李国然, 言天英

Computational Chemistry Design of the Experiment of Determining the Copper-Zinc Glavanic Battery Standard Electromotive Force

Yu'ang Liu, Xiaohong Liu, Shu Li, Shihai Ye, Guoran Li, Tianying Yan

表1 $ {{\Delta }}_{\text{sub}}{G} $，$ {{\Delta }}_{\text{ion}}{G} $和$ {\Delta }{{G}}_{\text{exp}}^{\text{*}} $相应电极反应的$ {{\Delta }}_{\text{r}}{{G}}_{\text{m, c, exp}}^{\text{Ө}}\text{和}{{\Delta }}_{\text{r}}{{G}}_{\text{m, a, exp}}^{\text{Ө}} $

电极 $ {{\Delta }}_{\text{sub}}{G}\text{/eV} $ [9] $ {{\Delta }}_{\text{ion}}{G}\text{/eV} $ [10] $ {\Delta }{{G}}_{\text{exp}}^{\text{*}}\text{/eV} $ [11] $ {{\Delta }}_{\text{r}}{{G}}_{\text{m, c, exp}}^{\text{Ө}}\text{/eV} $ $ {{\Delta }}_{\text{r}}{{G}}_{\text{m, a, exp}}^{\text{Ө}}\text{/eV} $ Cu 3.0836 28.0188 −21.7335 −9.3689 – Zn 0.9822 27.3589 −21.1638 – −7.1774