对“应用量子化学计算理解溶剂对CH3O−/CH3S−亲核性的影响”的思考与拓展
Comment and Improvement on "Understanding the Effect of Solvents on the Nucleophilicity of CH3O−/CH3S− Using Quantum Chemical Calculations"
对“应用量子化学计算理解溶剂对CH3O−/CH3S−亲核性的影响”的思考与拓展 |
| 宋哲轩, 胡阳, 吴翔钰, 谢静 |
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Comment and Improvement on "Understanding the Effect of Solvents on the Nucleophilicity of CH3O−/CH3S− Using Quantum Chemical Calculations" |
| Zhexuan Song, Yang Hu, Xiangyu Wu, Jing Xie |
| 图3 a) 亲核分子Y−的HOMO与底物CH3X的LUMO相互作用示意图；b) < LUMO底物 − HOMO亲核试剂 > 能级差–能垒关系图 |
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