仪器分析课程中绿色度概念的引入
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张红医, 何珺瑶, 石志红
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Introduction of the Concept of Greenness into Instrumental Analysis Course
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Hongyi Zhang, Junyao He, Zhihong Shi
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表1 常用试剂的总危害值(tHV)和总分析危害值(taHV) [14]
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| 类别 | 化合物名称 | CAS | tHV | taHV | | 烃类 | 戊烷(Pentane) | 109-66-0 | 23.4 | 36.4 | | 己烷(Hexane) | 110-54-3 | 53.8 | 81.4 | | 环己烷(Cyclohexane) | 110-82-7 | 57.9 | 79.8 | | 庚烷(Heptane) | 142-82-5 | 15.2 | 20.9 | | 异辛烷(Isooctane) | 540-84-1 | 57.1 | 79.2 | | 苯(Benzene) | 71-43-2 | 84 | 122 | | 甲苯(Toluene) | 108-88-3 | 43.9 | 60.5 | | 二甲苯(Xylenes) | 1330-20-7 | 51.5 | 68.2 | | 醇类 | 甲醇(Methanol) | 67-56-1 | 8.8 | 15.7 | | 乙醇(Ethanol) | 64-17-5 | 4.1 | 7.2 | | 异丙醇(Isopropanol) | 67-63-0 | 3.9 | 6.8 | | 庚醇(Heptanol) | 111-70-6 | 22.9 | 28.6 | | 辛醇(Octanol) | 111-87-5 | 38.3 | 45.7 | | 壬醇(Nonanol) | 143-08-8 | 39.8 | 46.7 | | 苯甲醇(Benzyl alcohol) | 100-51-6 | 45.2 | 55.1 | | 醚类 | 乙醚(Diethyl ether) | 60-29-7 | 8.7 | 16 | | Methyl tert-butyl ether | 1634-04-4 | 2.7 | 3.8 | | 四氢呋喃(Tetrahydrofuran) | 109-99-9 | 9.1 | 14.9 | | 醛类 | 糠醛(Furfural) | 98-08-1 | 47.7 | 69.2 | | 苯甲醛(Benzaldehyde) | 100-52-7 | 56.9 | 77.5 | | 酮类 | 丙酮(Acetone) | 67-64-1 | 1.5 | 2.6 | | 有机酸类 | 甲酸(Formic acid) | 64-18-6 | 25.8 | 43 | | 乙酸(Acetic acid) | 64-19-7 | 1.3 | 2.1 | | 丙酸(Propionic acid) | 79-19-4 | 27 | 41.2 | | 酯类 | 乙酸乙酯(Ethyl acetate) | 141-78-6 | 5 | 7.3 | | 氯化烃类 | 二氯甲烷(Dichloromethane) | 75-09-2 | 39.3 | 59.8 | | 氯仿(Chloroform) | 67-66-3 | 70.7 | 103.8 | | 四氯化碳(Carbon tetrachloride) | 56-23-5 | 80 | 109.7 | | 三氯乙烯(Trichloroethylene) | 79-01-6 | 90.9 | 125.1 | | 四氯乙烯(Tetrachloroethylene) | 127-18-4 | 82.7 | 107.7 | | 1.1.1-三氯乙烷(1.1.1-Trichloroethane) | 71-55-6 | 34.7 | 49 | | 1.1.2.2-四氯乙烷(1.1.2.2-Tetrachloroethane) | 79-34-5 | 76.9 | 97.3 | | 氯苯(Chlorobenzene) | 108-90-7 | 58 | 75.9 | | 其他试剂 | 乙腈(Acetonitrile) | 75-05-8 | 18.8 | 26.8 | | 二硫化碳(Carbon disulphide) | 75-15-0 | 61.6 | 89.6 |
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