过渡态理论对Arrhenius公式的诠释——以硝酸异丙酯与自由基反应为例
Interpretation of Arrhenius Formula by Transition State Theory: Taking the Reaction of Isopropyl Nitrate with Radicals as an Example
(a) 不含零点能校正；(b) 含零点能校正
过渡态理论对Arrhenius公式的诠释——以硝酸异丙酯与自由基反应为例 |
| 孙翠红, 许保恩, 刘迎, 杨静, 吕立强 |
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Interpretation of Arrhenius Formula by Transition State Theory: Taking the Reaction of Isopropyl Nitrate with Radicals as an Example |
| Cuihong Sun, Baoen Xu, Ying Liu, Jing Yang, Liqiang Lv |
| 图2 硝酸异丙酯与Cl原子、OH和NO3自由基反应的势能剖面图 (a) 不含零点能校正；(b) 含零点能校正 |
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