“受阻Lewis酸碱对”化学的研究进展

doi:10.3866/PKU.DXHX20160401

摘要/Abstract

摘要：

受阻Lewis酸碱对(Frustrated Lewis Pairs, FLPs)是一类具有特殊反应活性的Lewis酸碱对。自发现以来, FLPs受到了广泛关注并在许多领域崭露头角。本文对FLPs在不对称氢化、高分子聚合、CO₂催化还原等应用领域取得的突破进行了介绍;同时对过渡金属FLPs和FLPs配位的过渡金属催化体系进行了综述;最后对FLPs领域未来的发展前景进行了展望。

关键词: 受阻Lewis酸碱对, 不对称氢化, 离子型聚合反应, CO₂催化还原, 过渡金属催化体系

Abstract:

Frustrated Lewis Pairs (FLPs) represent a class of Lewis acids and bases possessing unique reactivities. Since their discovery, FLPs have obtained extensive attention and have grown rapidly on a broad range of studies. This paper highlights the application of FLPs in the fields of asymmetric hydrogenation, polymerization and catalytic reduction of CO₂. Transition-metal FLPs and complexes containing FLPs ligands are also reviewed. Finally the trend in the development of FLPs is also discussed.

Key words: Frustrated Lewis Pairs, Asymmetric hydrogenation, Ionic polymerization, Catalytic CO₂ reduction, Transition-metal catalytic systems

柳晗宇,杨中天,余子迪,米天雄,卞江. “受阻Lewis酸碱对”化学的研究进展[J]. 大学化学, 2016, 31(4): 1-11.

Han-Yu LIU,Zhong-Tian YANG,Zi-Di YU,Tian-Xiong MI,Jiang BIAN. Research Progress on Frustrated Lewis Pairs Chemistry[J]. University Chemistry, 2016, 31(4): 1-11.

链接本文: https://www.dxhx.pku.edu.cn/CN/10.3866/PKU.DXHX20160401

https://www.dxhx.pku.edu.cn/CN/Y2016/V31/I4/1

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