大学化学

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群论在化学中的应用:可约表示分解的口诀教学法

张建斌, 潘素娟, 王长青, 李志锋, 李会学   

  1. 天水师范大学化学工程与技术学院, 甘肃省先进光电功能材料重点实验室, 甘肃 天水 741000
  • 收稿日期:2026-06-29 录用日期:2026-08-07
  • 通讯作者: 李会学 E-mail:li_hx2001@126.com Huixue Li
  • 基金资助:
    甘肃省基础研究创新群体项目(24JRRE001);甘肃省陇原人才重点项目(2022RCXM087)

Application of group theory in chemistry: a mnemonic rhyme approach to the reduction of reducible representations

Jianbin Zhang, Sujuan Pan, Changqing Wang, Zhifeng Li, Huixue Li   

  1. College of Chemical Engineering and Technology, Key Laboratory of Advanced Optoelectronic Functional Materials of Gansu Province, Tianshui Normal University, Tianshui 741000, Gansu Province, China
  • Received:2026-06-29 Accepted:2026-08-07
  • Contact: Huixue Li E-mail:li_hx2001@126.com

摘要: 群论作为现代化学的基础数学工具,广泛应用于分子对称性研究、分子轨道理论及红外、拉曼光谱分析等领域。受理论抽象性限制,群表示相关内容教学难度较大,其中可约表示分解原理与运算过程晦涩难懂,是课程教学难点。为此,本文构建“骨肉口诀”教学法,打通抽象数理知识与直观物理图像之间的联系,阐释特征标内在含义,将复杂分解运算转化为清晰易懂的思维逻辑。该方法能够引导学生跳出公式机械计算,深刻理解对称性本质。经典型分子实例验证,该教学法可有效简化认知过程、提高计算正确率,缓解学生学习畏难心理,提升课堂教学效率,同时为化学专业群论课程教学方法创新提供优质实践案例与借鉴思路。

关键词: 群论, 可约表示, 不可约表示, 口诀教学

Abstract: Group theory, as a foundational mathematical tool in modern chemistry, is extensively employed in the study of molecular symmetry, molecular orbital theory, and infrared and Raman spectroscopy. Due to its inherently abstract nature, the instruction of group representation theory poses considerable pedagogical challenges. In particular, the principles and computational procedures involved in the reduction of reducible representations are notoriously difficult to grasp, representing a major hurdle in the curriculum. To address this issue, this paper introduces a “Bone-and-Flesh Mnemonic” teaching method, which establishes a connection between abstract mathematical concepts and intuitive physical pictures, elucidates the underlying significance of characters, and transforms complex reduction operations into clear, accessible reasoning processes. This approach encourages students to move beyond rote formula manipulation and develop a deeper understanding of the essence of symmetry. Validation through representative molecular examples demonstrates that this method effectively streamlines the cognitive process, enhances computational accuracy, alleviates students’ apprehension toward learning, and improves overall classroom efficiency. Furthermore, it offers a practical and valuable reference for pedagogical innovation in group theory courses for chemistry majors.

Key words: Group theory, Reducible representation, Irreducible representation, Mnemonic rhyme teaching