大学化学 >> 2016, Vol. 31 >> Issue (9): 24-28.doi: 10.3866/PKU.DXHX201512025

教学研究与改革 上一篇    下一篇

对结构化学中价键理论教学的若干思考

侯华,黄智超,王宝山*()   

  • 发布日期:2016-09-30
  • 通讯作者: 王宝山 E-mail:baoshan@whu.edu.cn
  • 基金资助:
    武汉大学教改项目(QYW201206)

Revisit on the Teaching of Valence Bond Theory in the Curriculum of Structural Chemistry

Hua HOU,Zhi-Chao HUANG,Bao-Shan WANG*()   

  • Published:2016-09-30
  • Contact: Bao-Shan WANG E-mail:baoshan@whu.edu.cn
  • Supported by:
    武汉大学教改项目(QYW201206)

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摘要：

通过追踪原始文献，分析结构化学中价键理论部分的教学内容，特别是对氧气分子基态电子结构的处理，发现价键理论不仅能够正确解释或预测分子结构，而且对芳香性、铁磁性等化学键本质的描述表现更优。

关键词: 价键理论, 化学键, 氧气, 芳香性

Abstract:

After extensive investigations on the valence bond theory in the curriculum of structural chemistry, it was found that the limitation or even failure of the valence bond theory especially for the double bond electronic structure of oxygen molecule does not exist. Valence theory is capable of not only rationalizing or predicting the molecular structures but also revealing the chemical nature for many properties such as aromaticity and ferromagneticity in comparison with molecular orbital theory.

Key words: Valence bond theory, Chemical bond, Oxygen, Aromaticity

MSC2000: 

  • O6