大学化学

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撕下“惰性”的伪装:氙的自传

唐凯歌, 杨明远, 刘军枫   

  1. 北京化工大学化学学院, 北京 100029
  • 收稿日期:2026-05-20 录用日期:2026-09-08
  • 通讯作者: 刘军枫 E-mail:ljf@mail.buct.edu.cn Junfeng Liu
  • 基金资助:
    北京化工大学2023年研究生校企合作课程建设项目(G-XQ202414);北京化工大学本科教育教学改革研究项目(2023BHDJY11)

Tearing off the “inert” disguise: the autobiography of xenon

Kaige Tang, Mingyuan Yang, Junfeng Liu   

  1. College of Chemistry, Beijing University of Chemical Technology, Beijing 100029, China
  • Received:2026-05-20 Accepted:2026-09-08
  • Contact: Junfeng Liu E-mail:ljf@mail.buct.edu.cn

摘要: 氙常被放在教科书的“惰性气体”一栏,这很容易让人以为,它在任何环境中都只会安静旁观。其实,“惰性”只是在常温、常压等特定条件下对氙的化学反应性的概括。本文以氙第一人称讲述四段现代科学经历:在地核级高压下与铁、镍形成化合物;把稳定同位素129Xe的核磁信号“放大”,用于脑组织成像;在精细设计的多孔材料中与氪分开;在特殊介质中与金直接成键。这些关于氙的奇妙故事里,有的是真正的化学反应,有的只是把核自旋、可极化性和吸附等物理特长派上用场,它们说明氙并非绝对的“佛系气体”,在不同环境里也可以展现出“活泼”的一面。

关键词: 氙, 稀有气体, 高压化学, 129Xe, Xe/Kr分离, Au-Xe键

Abstract: Xenon is often placed in the “inert gas” column of textbooks, which can easily suggest that it simply remains quiet under all conditions. In fact, “inert” describes xenon’s chemical reactivity only under particular conditions such as room temperature and pressure. Told in xenon’s first-person voice, this article presents four modern scientific episodes: forming compounds with iron and nickel under pressures comparable to those in Earth’s core; amplifying the nuclear magnetic resonance signal of stable 129Xe for brain-tissue imaging; separating xenon from krypton with carefully designed porous materials; and forming direct bonds with gold in a special medium. Some episodes involve genuine chemical reactions, whereas others make use of physical properties such as nuclear spin, polarizability, and adsorption. Together, they show that xenon is not an absolutely passive gas and can display a more reactive side in different environments.

Key words: Xenon, Noble gas, High-pressure chemistry, 129Xe, Xe/Kr separation, Au–Xe bond