键价理论的研究进展

doi:10.3969/j.issn.1000-8438.2007.06.001

摘要/Abstract

摘要： 键价理论源于20世纪20年代离子晶体结构的Pauling电价规则,至今已发展成为现代结构化学一个重要内容,广泛应用于化学、物理学、晶体学、材料科学以至分子生物学领域^[1]。作为现代结构化学的杰出先行者,Pauling在28岁时归纳出复杂离子晶体结构的5个经验规则。其中以第二规则(即电价规则)发展成为键价理论的影响最为深远,在科学方法论上有很多值得认真学习之处。这个理论以大量实测晶体结构数据作为依据,基本概念清晰明了,且其经验性质并未妨碍它广泛应用于包括离子键在内的各键型物相中有关结构化学的问题。因此,键价理论的物理基础及其研究进展必然引起我们极大的兴趣。

胡盛志. 键价理论的研究进展[J]. 大学化学, 2007, 22(6): 1-12.

胡盛志. 键价理论的研究进展[J]. University Chemistry, 2007, 22(6): 1-12.

链接本文: https://www.dxhx.pku.edu.cn/CN/10.3969/j.issn.1000-8438.2007.06.001

https://www.dxhx.pku.edu.cn/CN/Y2007/V22/I6/1

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