无机白磷(P4)活化合成有机磷化合物的研究进展

doi:10.12461/PKU.DXHX202404063

大学化学 >> 2024, Vol. 39 >> Issue (12): 185-201.doi: 10.12461/PKU.DXHX202404063

所属专题：有机磷化学

无机白磷(P₄)活化合成有机磷化合物的研究进展

王丰晓, 苗志伟

南开大学化学学院, 元素有机化学国家重点实验室, 天津 300071

收稿日期:2024-04-10 录用日期:2024-07-24 发布日期:2024-12-17
通讯作者: 苗志伟 E-mail:miaozhiwei@nankai.edu.cn
基金资助:
国家自然科学基金面上项目(22071113);福建省南平市科技项目(N2020Z008)

Recent Advances in the Synthesis of Organic Phosphorus Compounds via Activation of Inorganic White Phosphorus

Fengxiao Wang, Zhiwei Miao

State Key Laboratory of Elemento-Organic Chemistry, College of Chemistry, Nankai University, Tianjin 300071, China

Received:2024-04-10 Accepted:2024-07-24 Published:2024-12-17
Contact: Zhiwei Miao E-mail:miaozhiwei@nankai.edu.cn

摘要/Abstract

摘要： 有机磷化合物在有机化学、农药和材料等领域具有重要应用，白磷(P₄)是现代磷化工最重要的原料之一，是制备有机磷化合物常见的磷原子源。近年来科研人员一直在研究白磷的化学性质，希望开发出直接将无机白磷转化为含磷功能化合物的方法。从无机白磷出发直接合成有机磷化合物将避开目前磷化工所依赖的多步骤传统工序，在保护环境的同时可以降低生产成本。本文综述了近年来从无机白磷出发直接合成有机磷化合物的研究进展，并对该领域的发展前景进行了展望。

关键词: 白磷活化, 有机磷化合物, 直接官能化

Abstract: Organic phosphorus compounds play a crucial role in various fields, including organic chemistry, agriculture, and materials science. White phosphorus (P₄) is a key raw material in the modern phosphorus chemical industry and serves as a common source of phosphorus atoms for the synthesis of organic phosphorus compounds. In recent years, researchers have focused on exploring the chemical properties of white phosphorus with the aim of developing methods for the direct conversion of inorganic white phosphorus into phosphorus-containing functional compounds. This approach not only circumvents the multi-step traditional processes currently employed in the phosphorus chemical industry but also contributes to environmental protection and cost reduction. This article reviews the recent advancements in the direct synthesis of organic phosphorus compounds from inorganic white phosphorus and discusses the future prospects for development in this area.

Key words: White phosphorus activation, Organic phosphorus compounds, Direct functionalization

王丰晓, 苗志伟. 无机白磷(P₄)活化合成有机磷化合物的研究进展[J]. 大学化学, 2024, 39(12): 185-201.

Fengxiao Wang, Zhiwei Miao. Recent Advances in the Synthesis of Organic Phosphorus Compounds via Activation of Inorganic White Phosphorus[J]. University Chemistry, 2024, 39(12): 185-201.

链接本文: https://www.dxhx.pku.edu.cn/CN/10.12461/PKU.DXHX202404063

https://www.dxhx.pku.edu.cn/CN/Y2024/V39/I12/185

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无机白磷(P₄)活化合成有机磷化合物的研究进展

Recent Advances in the Synthesis of Organic Phosphorus Compounds via Activation of Inorganic White Phosphorus

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