BiVO4基光阳极用于太阳能水分解性能的研究进展

doi:10.12461/PKU.DXHX202507100

摘要/Abstract

摘要： 光电化学(PEC)水分解是将太阳能转化成氢能的关键技术之一。在众多半导体光阳极材料中，BiVO₄因其适中的带隙(2.4-2.5 eV)、良好的化学稳定性、环境友好以及易于合成等优点，被视为是一种极具潜力的候选材料。然而，其PEC效率受到载流子迁移速率以及严重的体相与表面复合的限制。近期研究表明，通过针对性的改性策略可以有效克服这些瓶颈，显著提升BiVO₄的光电化学性能。本文系统综述了关键的优化策略，包括纳米结构调控、掺杂(本征/外源)、异质结构筑、表面钝化以及助催化剂负载，并分析了这些策略对电荷分离与传输动力学的影响。最后，对BiVO₄基光电化学系统未来的研究方向进行了展望。

关键词: 光电化学, BiVO₄基光阳极, 水分解, 载流子

Abstract: Photoelectrochemical (PEC) water splitting represents a pivotal technology for solar-to-hydrogen energy conversion. Among semiconductor photoanode materials, BiVO₄ has emerged as a highly promising candidate owing to its optimal bandgap (2.4-2.5 eV), exceptional chemical stability, environmental inertness, and facile synthesis. Nevertheless, its PEC efficiency is constrained by sluggish charge carrier transport kinetics and substantial bulk/surface recombination. Recent studies have demonstrated that these limitations can be effectively mitigated through targeted modification strategies, leading to significant enhancements in the photoelectrochemical performance of the BiVO₄. This review systematically examines key optimization approaches, including nanostructure engineering, doping (intrinsic/extrinsic), heterojunction construction, surface passivation, and cocatalyst loading, while evaluating their impacts on charge separation and transport dynamics. Finally, we present perspectives on future research directions to advance BiVO₄-based PEC systems.

Key words: Photoelectrochemistry, BiVO₄-based photoanodes, Water splitting, Charge carrier

高瑞廷, 郭笑天, 王蕾. BiVO₄基光阳极用于太阳能水分解性能的研究进展[J]. 大学化学, 2026, 41(8): 162-175.

Rui-Ting Gao, Xiaotian Guo, Lei Wang. Advances in BiVO₄-based photoanodes for solar water splitting performance[J]. University Chemistry, 2026, 41(8): 162-175.

链接本文: https://www.dxhx.pku.edu.cn/CN/10.12461/PKU.DXHX202507100

https://www.dxhx.pku.edu.cn/CN/Y2026/V41/I8/162

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BiVO₄基光阳极用于太阳能水分解性能的研究进展

Advances in BiVO₄-based photoanodes for solar water splitting performance

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