大学化学 >> 2016, Vol. 31 >> Issue (5): 68-72.doi: 10.3866/PKU.DXHX201506003

师生笔谈 上一篇    下一篇

通过实验教学探讨配位化学基本概念

陈水生*(),盛良全,乔瑞,杨松   

  • 发布日期:2016-05-23
  • 通讯作者: 陈水生 E-mail:chenss@fync.edu.cn
  • 基金资助:
    国家自然科学基金项目(2117104);安徽省高校振兴计划重大教研项目(2014zdjy081);优秀教研室(2013JCJS01)

Exploration on the Basic Concept of Coordination Chemistry via Laboratory Teaching

Shui-Sheng CHEN*(),Liang-Quan SHENG,Rui QIAO,Song YANG   

  • Published:2016-05-23
  • Contact: Shui-Sheng CHEN E-mail:chenss@fync.edu.cn
  • Supported by:
    国家自然科学基金项目(2117104);安徽省高校振兴计划重大教研项目(2014zdjy081);优秀教研室(2013JCJS01)

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摘要：

以4-咪唑基苯甲酸(H2L)为配体,与硝酸铜反应合成铜的配合物[CuIICuI(HL)(L)(H2O)2]·H2O。通过配合物的合成、结构表征、结构分析的实验教学过程,引导学生挖掘并理解配位化学学科的基本概念及理论,培养学生将理论与实践相互结合的能力,促进学生自身知识体系的构建。

关键词: 配位化学, 实验教学, 理论知识体系

Abstract:

The synthesis of a copper complex [CuIICuI(HL)(L)(H2O)2]·H2O based on the hydrothermal synthesis of 4-(1H-imidazol-4-yl)benzoic acid (H2L) with Cu(II) cation, was taken as laboratory teaching project for undergraduates, which covered the aspects of the designed synthesis, structural characterization and analysis. The aim of the laboratory teaching is to enhance the theoretical knowledge of coordination chemistry, promote the mutual integration between the theoretical knowledge and laboratory skills, and facilitate the construction of comprehensive knowledge system for undergraduates.

Key words: Coordination chemistry, Laboratory teaching, Theoretical knowledge system