大学化学 >> 2024, Vol. 39 >> Issue (5): 98-107.doi: 10.3866/PKU.DXHX202310026

所属专题： 第4届全国大学生化学实验创新设计大赛

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基于锌空电池探究能斯特方程影响因素及固态锌空电池的应用

高文琪, 范晓艳, 王飞翔, 傅镯君, 张璟, 胡恩来, 宫培军   

  1. 浙江师范大学化学与材料科学学院, 浙江 金华 321019
  • 收稿日期:2023-10-10 修回日期:2024-02-02 发布日期:2024-03-11
  • 通讯作者: 张璟, 胡恩来, 宫培军 E-mail:jingzhang@zjnu.edu.cn;huenlai@zjnu.edu.cn;skygpj@zjnu.cn
  • 基金资助:
    国家级大学生创新创业训练计划项目(202310345011)；国家自然科学基金青年项目(22209150)；浙江省课程思政示范课程《无机化学（一、二）》项目(2022-72)；浙江师范大学初阳学院课程建设资助项目(2024-14)

Exploring Nernst Equation Factors and Applications of Solid Zinc-Air Battery

Wenqi Gao, Xiaoyan Fan, Feixiang Wang, Zhuojun Fu, Jing Zhang, Enlai Hu, Peijun Gong   

  1. College of Chemistry and Materials Science, Zhejiang Normal University, Jinhua 321019, Zhejiang Province, China
  • Received:2023-10-10 Revised:2024-02-02 Published:2024-03-11
  • Contact: Jing Zhang, Enlai Hu, Peijun Gong E-mail:jingzhang@zjnu.edu.cn;huenlai@zjnu.edu.cn;skygpj@zjnu.cn

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摘要： 针对无机化学中能斯特方程的教学难点，本实验引入紧跟科学前沿的锌空电池为教学模型，通过改变电极氧化型和还原型浓度来探究能斯特方程影响因素，加深学生对于电化学过程的理解。同时将柔性电子技术引入实验课堂，以安全环保的卡拉胶作为固态电解质，引导学生学习、搭建固态锌空电池，并对其进行电池电压与弯曲角度的性能测试。此外，培养学生创造力，自主设计搭建多形态固态锌空电池，并对用电器进行供电。本实验紧密结合基础电化学知识，密切联系科研前端技术，使学生在加深对能斯特方程理解的同时，能够认识和制作柔性电子器件，激发学生对电化学课程的学习兴趣，且教学成本低、效果好。

关键词: 能斯特方程, 锌空电池, 柔性电子, 固态电解质

Abstract: Addressing the challenges in teaching the Nernst equation in inorganic chemistry, this experiment introduces the cutting-edge zinc-air battery as a teaching model. By altering the concentration of oxidizing and reducing materials, students explore the key factors of the Nernst equation, enhancing their understanding of electrochemical processes. Simultaneously, the experiment incorporates flexible electronics technology, using carrageenan as a safe and environmentally friendly solid electrolyte to guide students in learning and constructing solid zinc-air batteries. The batteries are tested for voltage performance at various bending angles to assess their flexibility. Moreover, to foster creativity, students design and build various forms of solid zinc-air batteries to power electronic devices. This experiment is closely aligned with fundamental electrochemical knowledge and state-of-the-art technology, allowing students to deepen their understanding of the Nernst equation while gaining practical experience in creating flexible electronic devices. This approach sparks students’ interest in electrochemistry and proves cost-effective with promising results.

Key words: Nernst equation, Zinc-air battery, Flexible electronics, Solid electrolyte