大学化学 >> 2022, Vol. 37 >> Issue (5): 2111037.doi: 10.3866/PKU.DXHX202111037

所属专题: 第2届全国大学生化学实验创新设计竞赛

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光学魔术——斑斓的微结构色

杨袁栋, 邓慧丰, 林思奇, 袁亚利()   

  • 收稿日期:2021-11-11 录用日期:2021-11-29 发布日期:2022-03-25
  • 通讯作者: 袁亚利 E-mail:thanksin2013@163.com
  • 作者简介:袁亚利, Email: thanksin2013@163.com
  • 基金资助:
    国家自然科学基金(21765005);广西自然科学基金(2020GXNSFBA297116);广西自然科学基金(桂科AD19110096)

Optical Magic: The Bizarre Microstructure Color

Yuandong Yang, Huifeng Deng, Siqi Lin, Yali Yuan()   

  • Received:2021-11-11 Accepted:2021-11-29 Published:2022-03-25
  • Contact: Yali Yuan E-mail:thanksin2013@163.com

摘要:

自然界中的一些颜色是由非常精细的微米级结构或者纳米级结构而形成的结构色。这种结构色是生物体亚显微结构形成,通常具有光泽,颜色会随视角发生变化,例如蝴蝶翅色、一些鸟类羽毛、甲虫体壁表面等。结构色具有不褪色和环保等优点,通过对自然界中结构色的研究可以促进防伪、装饰等领域的发展。本实验采用了一种绿色简单的方法,将廉价易得的正硅酸乙酯与氨水简单混合即可得到均匀的二氧化硅纳米颗粒。通过改变正硅酸乙酯和氨水的加入量可以调节二氧化硅纳米颗粒的粒径,从而获得不同结构色的悬浮性墨水,可直接用于书写或绘制结构色图案,有望用于低成本制备彩色颜料。

关键词: 光子晶体, SiO2微球, 微结构色

Abstract:

Some colors in nature are structural colors with very fine structures at the micrometer or nanometer scale. These structural colors are usually shiny and change with the angle of view, such as the color of butterflies' wings, the color of birds' feathers, the surface of sea shell and beetle, etc. Due to the advantages of fastness, environmental friendliness, and iridescent effect, structural color has a broad application prospect in display, decoration and anti-counterfeiting fields. In this experiment, a green and simple method was used to obtain the monodisperse silica nanoparticles by simply mixing cheap and readily available ethyl orthosilicate with ammonia hydroxide. By changing the ethyl orthosilicate to ammonia hydroxide ratio, the particle size of silica nanoparticles can be tuned, so that suspension inks with different structural colors can be obtained. The resulted silica nanoparticles can be directly used for writing or drawing structural color patterns, and are expected to be used in low-cost color pigment preparation.

Key words: Photonic crystal, Silica microsphere, Structural color